Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol
24(S)-Homoethylcastasterone belongs to the group of natural products named brassinosteroids. This work reports its synthesis from stigmasterol through a new pathway which involves a reductive opening of a 5β,6β-steroidal epoxide derivative. Key intermediate compound 4a also allows to develop pathway...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p104_TemeCenturion |
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todo:paper_03650375_v86_n3-6_p104_TemeCenturion2023-10-03T15:27:49Z Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol Teme Centurión, O.M. Galagovsky, L.R. 24(S)-Homoethylcastasterone belongs to the group of natural products named brassinosteroids. This work reports its synthesis from stigmasterol through a new pathway which involves a reductive opening of a 5β,6β-steroidal epoxide derivative. Key intermediate compound 4a also allows to develop pathways for the synthesis of highly active C-3 natural oxygenated brassinosteroids. Fil:Teme Centurión, O.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p104_TemeCenturion |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
24(S)-Homoethylcastasterone belongs to the group of natural products named brassinosteroids. This work reports its synthesis from stigmasterol through a new pathway which involves a reductive opening of a 5β,6β-steroidal epoxide derivative. Key intermediate compound 4a also allows to develop pathways for the synthesis of highly active C-3 natural oxygenated brassinosteroids. |
| format |
JOUR |
| author |
Teme Centurión, O.M. Galagovsky, L.R. |
| spellingShingle |
Teme Centurión, O.M. Galagovsky, L.R. Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol |
| author_facet |
Teme Centurión, O.M. Galagovsky, L.R. |
| author_sort |
Teme Centurión, O.M. |
| title |
Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol |
| title_short |
Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol |
| title_full |
Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol |
| title_fullStr |
Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol |
| title_full_unstemmed |
Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol |
| title_sort |
alternative synthesis of (24s)-homoethylcastasterone from stigmasterol |
| url |
http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p104_TemeCenturion |
| work_keys_str_mv |
AT temecenturionom alternativesynthesisof24shomoethylcastasteronefromstigmasterol AT galagovskylr alternativesynthesisof24shomoethylcastasteronefromstigmasterol |
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1782023832290197504 |