Synthesis of [21‐13C]‐cholesterol

The synthesis of [21‐13C]‐cholesterol (5) from 3β‐O‐(t‐butyldimethylsilyl)‐17β‐cyano‐androst‐5‐ene (1) is described. Labelled carbon‐atom was introduced by Grignard reaction of nitrile derivative with [13C]‐methylmagnesium iodide. Location of label was confirmed by 13C‐NMR spectroscopy. Copyright ©...

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Detalles Bibliográficos
Autores principales:	Caballero, G.M., Gros, E.G.
Formato:	JOUR
Materias:	synthesis [21‐13C]‐cholesterol carbon 13 cholesterol article cholesterol synthesis controlled study isotope labeling
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_03624803_v34_n2_p127_Caballero
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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