Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine
The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_03624803_v23_n1_p109_Doller |
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todo:paper_03624803_v23_n1_p109_Doller2023-10-03T15:27:05Z Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine Doller, D. Gros, E.G. |2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure was checked by physical (1H and 13C NMR, MS) methods. Copyright © 1986 John Wiley & Sons, Ltd. Fil:Doller, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03624803_v23_n1_p109_Doller |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
|2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 |
| spellingShingle |
|2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 Doller, D. Gros, E.G. Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| topic_facet |
|2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 |
| description |
The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure was checked by physical (1H and 13C NMR, MS) methods. Copyright © 1986 John Wiley & Sons, Ltd. |
| format |
JOUR |
| author |
Doller, D. Gros, E.G. |
| author_facet |
Doller, D. Gros, E.G. |
| author_sort |
Doller, D. |
| title |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_short |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_full |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_fullStr |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_full_unstemmed |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_sort |
preparation of |2,4‐2h|‐ and |2,4‐3h|‐tomatidine |
| url |
http://hdl.handle.net/20.500.12110/paper_03624803_v23_n1_p109_Doller |
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AT dollerd preparationof242hand243htomatidine AT groseg preparationof242hand243htomatidine |
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1782027382993977344 |