The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent

[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidat...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Doctorovich, F., Granara, M., Di Salvo, F.
Formato: JOUR
Materias:
Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.

Ejemplares similares