The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent

[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidat...

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Detalles Bibliográficos
Autores principales: Doctorovich, F., Granara, M., Di Salvo, F.
Formato: JOUR
Materias:
Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_03404285_v26_n4-5_p505_Doctorovich
record_format dspace
spelling todo:paper_03404285_v26_n4-5_p505_Doctorovich2023-10-03T15:25:35Z The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent Doctorovich, F. Granara, M. Di Salvo, F. Agents Amines Chemistry Chromatography Coordination reactions Iron compounds Oxidation Ruthenium compounds Benzylamine Benzylphenylmethanimine Nitrosyl Oxidation products Oxidizing agents Chemical reactions [Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Di Salvo, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
spellingShingle Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
Doctorovich, F.
Granara, M.
Di Salvo, F.
The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
topic_facet Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
description [Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.
format JOUR
author Doctorovich, F.
Granara, M.
Di Salvo, F.
author_facet Doctorovich, F.
Granara, M.
Di Salvo, F.
author_sort Doctorovich, F.
title The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_short The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_full The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_fullStr The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_full_unstemmed The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_sort reaction of [ru(bpy)2(no)cl]2+ and [fe(cn)5no]2- with benzylamine: coordinated nitrosyl as an oxidizing agent
url http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
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