Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes

Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reacti...

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Detalles Bibliográficos
Autores principales: Escola, N., Llebaría, A., Leitus, G., Doctorovich, F.
Formato: JOUR
Materias:
Chemical reactions
Crystal structure
Olefins
X ray diffraction
C-nitrosochloroalkanes
Cyclooctene
Electrophilic
NOCl
Potassium compounds
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society.

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