Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes

Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reacti...

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Autores principales: Escola, N., Llebaría, A., Leitus, G., Doctorovich, F.
Formato: JOUR
Materias:
Chemical reactions
Crystal structure
Olefins
X ray diffraction
C-nitrosochloroalkanes
Cyclooctene
Electrophilic
NOCl
Potassium compounds
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_02767333_v25_n16_p3799_Escola2023-10-03T15:16:00Z Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes Escola, N. Llebaría, A. Leitus, G. Doctorovich, F. Chemical reactions Crystal structure Olefins X ray diffraction C-nitrosochloroalkanes Cyclooctene Electrophilic NOCl Potassium compounds Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society. Fil:Escola, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Llebaría, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Chemical reactions
Crystal structure
Olefins
X ray diffraction
C-nitrosochloroalkanes
Cyclooctene
Electrophilic
NOCl
Potassium compounds
spellingShingle Chemical reactions
Crystal structure
Olefins
X ray diffraction
C-nitrosochloroalkanes
Cyclooctene
Electrophilic
NOCl
Potassium compounds
Escola, N.
Llebaría, A.
Leitus, G.
Doctorovich, F.
Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
topic_facet Chemical reactions
Crystal structure
Olefins
X ray diffraction
C-nitrosochloroalkanes
Cyclooctene
Electrophilic
NOCl
Potassium compounds
description Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society.
format JOUR
author Escola, N.
Llebaría, A.
Leitus, G.
Doctorovich, F.
author_facet Escola, N.
Llebaría, A.
Leitus, G.
Doctorovich, F.
author_sort Escola, N.
title Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_short Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_full Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_fullStr Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_full_unstemmed Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_sort formation of coordinated c-nitroso compounds by reaction of k[ircl 5no] with alkenes
url http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
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AT llebariaa formationofcoordinatedcnitrosocompoundsbyreactionofkircl5nowithalkenes
AT leitusg formationofcoordinatedcnitrosocompoundsbyreactionofkircl5nowithalkenes
AT doctorovichf formationofcoordinatedcnitrosocompoundsbyreactionofkircl5nowithalkenes
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