Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, cryst...
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| Autores principales: | , , , , |
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| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_02767333_v24_n20_p4707_Doctorovich |
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| Sumario: | In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, crystal structures could be determined by X-ray diffraction. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce; moreover, to our knowledge this is the first example of isolated primary nitrosamines coordinated to a metal center through the NO moiety. © 2005 American Chemical Society. |
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