Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines

In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, cryst...

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Detalles Bibliográficos
Autores principales:	Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L.
Formato:	JOUR
Materias:	Complexation Coordination reactions Crystal structure Organometallics Potassium compounds X ray diffraction analysis Coordinated nitrosamines Ligands Metal center P-toluidine Nitrosamines
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_02767333_v24_n20_p4707_Doctorovich
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_02767333_v24_n20_p4707_Doctorovich
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spelling	todo:paper_02767333_v24_n20_p4707_Doctorovich2023-10-03T15:15:59Z Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines Doctorovich, F. Di Salvo, F. Escola, N. Trápani, C. Shimon, L. Complexation Coordination reactions Crystal structure Organometallics Potassium compounds X ray diffraction analysis Coordinated nitrosamines Ligands Metal center P-toluidine Nitrosamines In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, crystal structures could be determined by X-ray diffraction. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce; moreover, to our knowledge this is the first example of isolated primary nitrosamines coordinated to a metal center through the NO moiety. © 2005 American Chemical Society. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02767333_v24_n20_p4707_Doctorovich
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Complexation Coordination reactions Crystal structure Organometallics Potassium compounds X ray diffraction analysis Coordinated nitrosamines Ligands Metal center P-toluidine Nitrosamines
spellingShingle	Complexation Coordination reactions Crystal structure Organometallics Potassium compounds X ray diffraction analysis Coordinated nitrosamines Ligands Metal center P-toluidine Nitrosamines Doctorovich, F. Di Salvo, F. Escola, N. Trápani, C. Shimon, L. Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
topic_facet	Complexation Coordination reactions Crystal structure Organometallics Potassium compounds X ray diffraction analysis Coordinated nitrosamines Ligands Metal center P-toluidine Nitrosamines
description	In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, crystal structures could be determined by X-ray diffraction. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce; moreover, to our knowledge this is the first example of isolated primary nitrosamines coordinated to a metal center through the NO moiety. © 2005 American Chemical Society.
format	JOUR
author	Doctorovich, F. Di Salvo, F. Escola, N. Trápani, C. Shimon, L.
author_facet	Doctorovich, F. Di Salvo, F. Escola, N. Trápani, C. Shimon, L.
author_sort	Doctorovich, F.
title	Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
title_short	Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
title_full	Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
title_fullStr	Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
title_full_unstemmed	Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
title_sort	formation of coordinated nitrosamines by reaction of k[ircl5no] with primary amines
url	http://hdl.handle.net/20.500.12110/paper_02767333_v24_n20_p4707_Doctorovich
work_keys_str_mv	AT doctorovichf formationofcoordinatednitrosaminesbyreactionofkircl5nowithprimaryamines AT disalvof formationofcoordinatednitrosaminesbyreactionofkircl5nowithprimaryamines AT escolan formationofcoordinatednitrosaminesbyreactionofkircl5nowithprimaryamines AT trapanic formationofcoordinatednitrosaminesbyreactionofkircl5nowithprimaryamines AT shimonl formationofcoordinatednitrosaminesbyreactionofkircl5nowithprimaryamines
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Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines

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