Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)

Studies of the reaction of lithium morpholide with N,N-dibutylformamide and 1-formyl-piperidine, respectively, indicate that in the complex equilibria resulting from these compounds the mixed diamino lithium alkoxides derived from morpholine and the corresponding amide (N,N-dibutylformamide or 1-for...

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Autores principales: Nudelman, N.S., Schulz, H., Liñares, G.G., Bonatti, A., Boche, G.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_02767333_v17_n2_p146_Nudelman
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_02767333_v17_n2_p146_Nudelman2023-10-03T15:15:58Z Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H) Nudelman, N.S. Schulz, H. Liñares, G.G. Bonatti, A. Boche, G. Studies of the reaction of lithium morpholide with N,N-dibutylformamide and 1-formyl-piperidine, respectively, indicate that in the complex equilibria resulting from these compounds the mixed diamino lithium alkoxides derived from morpholine and the corresponding amide (N,N-dibutylformamide or 1-formylpiperidine) are formed first. These intermediates then collapse to the lithium morpholide carbamoyl anion which reacts with morpholine to finally give the lithium dimorpholinemethoxide, which was detected by 13C NMR as well as independently synthesized. Fil:Schulz, H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02767333_v17_n2_p146_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Studies of the reaction of lithium morpholide with N,N-dibutylformamide and 1-formyl-piperidine, respectively, indicate that in the complex equilibria resulting from these compounds the mixed diamino lithium alkoxides derived from morpholine and the corresponding amide (N,N-dibutylformamide or 1-formylpiperidine) are formed first. These intermediates then collapse to the lithium morpholide carbamoyl anion which reacts with morpholine to finally give the lithium dimorpholinemethoxide, which was detected by 13C NMR as well as independently synthesized.
format JOUR
author Nudelman, N.S.
Schulz, H.
Liñares, G.G.
Bonatti, A.
Boche, G.
spellingShingle Nudelman, N.S.
Schulz, H.
Liñares, G.G.
Bonatti, A.
Boche, G.
Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
author_facet Nudelman, N.S.
Schulz, H.
Liñares, G.G.
Bonatti, A.
Boche, G.
author_sort Nudelman, N.S.
title Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_short Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_full Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_fullStr Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_full_unstemmed Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_sort further insights into the chemistry of acyllithium compounds r2nc(o)li: characterization of an amide (r2nli) adduct (r2nchnr2(oli)) to a formamide (r2nc(o)h)
url http://hdl.handle.net/20.500.12110/paper_02767333_v17_n2_p146_Nudelman
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