Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
Alginate of known copolymer composition was applied to antioxidant film developed by loading L-(+)-ascorbic (AA) and citric (CA) acids. Relative humidity (RH, 33.3-75.2%) of storage (25.0 °C) and glycerol (plasticizer) level, separately and through their interaction, decreased the AA hydrolytic stab...
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todo:paper_02608774_v175_n_p1_DeNobili2023-10-03T15:11:59Z Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation De'Nobili, M.D. Soria, M. Martinefski, M.R. Tripodi, V.P. Fissore, E.N. Rojas, A.M. Alginate copolymer Antioxidant films Ascorbic acid hydrolysis Citric acid Glycerol Alginate Antioxidants Citric acid Food preservation Food storage Glycerol Interfaces (materials) Organic acids Acid hydrolysis Antioxidant films Copolymer compositions Glycerol (plasticizer) Hydrolytic stability L(+)-ascorbic acid Polymeric networks Water penetration Ascorbic acid Alginate of known copolymer composition was applied to antioxidant film developed by loading L-(+)-ascorbic (AA) and citric (CA) acids. Relative humidity (RH, 33.3-75.2%) of storage (25.0 °C) and glycerol (plasticizer) level, separately and through their interaction, decreased the AA hydrolytic stability and, hence, the antioxidant half-life of films. Glycerol can facilitate the water penetration from the environment into the polymeric network. The CA content did not vary during film storage. Film browning was then associated to AA degradation. However, CA slowed down the browning development at longer storage times because of the changes in the kinetic order. It may catalyze the formation of unstable color compounds. The present work permitted to determine that AA and CA were 100% recovered after film casting. Also, it allowed finding the adequate film composition and period where the alginate film supporting AA and CA can be used as an antioxidant active interface for food preservation. © 2015 Published by Elsevier Ltd. Fil:Soria, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fissore, E.N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Rojas, A.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02608774_v175_n_p1_DeNobili |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Alginate copolymer Antioxidant films Ascorbic acid hydrolysis Citric acid Glycerol Alginate Antioxidants Citric acid Food preservation Food storage Glycerol Interfaces (materials) Organic acids Acid hydrolysis Antioxidant films Copolymer compositions Glycerol (plasticizer) Hydrolytic stability L(+)-ascorbic acid Polymeric networks Water penetration Ascorbic acid |
spellingShingle |
Alginate copolymer Antioxidant films Ascorbic acid hydrolysis Citric acid Glycerol Alginate Antioxidants Citric acid Food preservation Food storage Glycerol Interfaces (materials) Organic acids Acid hydrolysis Antioxidant films Copolymer compositions Glycerol (plasticizer) Hydrolytic stability L(+)-ascorbic acid Polymeric networks Water penetration Ascorbic acid De'Nobili, M.D. Soria, M. Martinefski, M.R. Tripodi, V.P. Fissore, E.N. Rojas, A.M. Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
topic_facet |
Alginate copolymer Antioxidant films Ascorbic acid hydrolysis Citric acid Glycerol Alginate Antioxidants Citric acid Food preservation Food storage Glycerol Interfaces (materials) Organic acids Acid hydrolysis Antioxidant films Copolymer compositions Glycerol (plasticizer) Hydrolytic stability L(+)-ascorbic acid Polymeric networks Water penetration Ascorbic acid |
description |
Alginate of known copolymer composition was applied to antioxidant film developed by loading L-(+)-ascorbic (AA) and citric (CA) acids. Relative humidity (RH, 33.3-75.2%) of storage (25.0 °C) and glycerol (plasticizer) level, separately and through their interaction, decreased the AA hydrolytic stability and, hence, the antioxidant half-life of films. Glycerol can facilitate the water penetration from the environment into the polymeric network. The CA content did not vary during film storage. Film browning was then associated to AA degradation. However, CA slowed down the browning development at longer storage times because of the changes in the kinetic order. It may catalyze the formation of unstable color compounds. The present work permitted to determine that AA and CA were 100% recovered after film casting. Also, it allowed finding the adequate film composition and period where the alginate film supporting AA and CA can be used as an antioxidant active interface for food preservation. © 2015 Published by Elsevier Ltd. |
format |
JOUR |
author |
De'Nobili, M.D. Soria, M. Martinefski, M.R. Tripodi, V.P. Fissore, E.N. Rojas, A.M. |
author_facet |
De'Nobili, M.D. Soria, M. Martinefski, M.R. Tripodi, V.P. Fissore, E.N. Rojas, A.M. |
author_sort |
De'Nobili, M.D. |
title |
Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
title_short |
Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
title_full |
Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
title_fullStr |
Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
title_full_unstemmed |
Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
title_sort |
stability of l-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation |
url |
http://hdl.handle.net/20.500.12110/paper_02608774_v175_n_p1_DeNobili |
work_keys_str_mv |
AT denobilimd stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation AT soriam stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation AT martinefskimr stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation AT tripodivp stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation AT fissoreen stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation AT rojasam stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation |
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1807319022005387264 |