Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface
The study of the structure of the electrode–solution interface usually involves the measurement of the differential capacity–potential characteristics of the system. In order to obtain the double‐layer parameters from these data, integration and differentiation procedures are required and, for this...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01928651_v2_n3_p221_Batana |
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todo:paper_01928651_v2_n3_p221_Batana2023-10-03T15:09:09Z Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface Batana, A. Filho, R.C.R. Avaca, L.A. González, E.R. The study of the structure of the electrode–solution interface usually involves the measurement of the differential capacity–potential characteristics of the system. In order to obtain the double‐layer parameters from these data, integration and differentiation procedures are required and, for this purpose, the use of computational methods is of great value. Two computer programs have been written for the treatment of data for the adsorption of neutral molecules on electrodes. The programs use the charge density and the electrode potential as the electrical variable, respectively, and, in both cases, the differentiation procedures have been optimized by the use of an adequate numerical function. The advantages of doing a simultaneous analysis on both electrical variables are pointed out. Copyright © 1981 John Wiley & Sons, Inc. Fil:Batana, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:González, E.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01928651_v2_n3_p221_Batana |
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Universidad de Buenos Aires |
| institution_str |
I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The study of the structure of the electrode–solution interface usually involves the measurement of the differential capacity–potential characteristics of the system. In order to obtain the double‐layer parameters from these data, integration and differentiation procedures are required and, for this purpose, the use of computational methods is of great value. Two computer programs have been written for the treatment of data for the adsorption of neutral molecules on electrodes. The programs use the charge density and the electrode potential as the electrical variable, respectively, and, in both cases, the differentiation procedures have been optimized by the use of an adequate numerical function. The advantages of doing a simultaneous analysis on both electrical variables are pointed out. Copyright © 1981 John Wiley & Sons, Inc. |
| format |
JOUR |
| author |
Batana, A. Filho, R.C.R. Avaca, L.A. González, E.R. |
| spellingShingle |
Batana, A. Filho, R.C.R. Avaca, L.A. González, E.R. Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| author_facet |
Batana, A. Filho, R.C.R. Avaca, L.A. González, E.R. |
| author_sort |
Batana, A. |
| title |
Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| title_short |
Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| title_full |
Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| title_fullStr |
Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| title_full_unstemmed |
Determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| title_sort |
determination of electrical double‐layer parameters for the adsorption of neutral molecules at the electrode–solution interface |
| url |
http://hdl.handle.net/20.500.12110/paper_01928651_v2_n3_p221_Batana |
| work_keys_str_mv |
AT batanaa determinationofelectricaldoublelayerparametersfortheadsorptionofneutralmoleculesattheelectrodesolutioninterface AT filhorcr determinationofelectricaldoublelayerparametersfortheadsorptionofneutralmoleculesattheelectrodesolutioninterface AT avacala determinationofelectricaldoublelayerparametersfortheadsorptionofneutralmoleculesattheelectrodesolutioninterface AT gonzalezer determinationofelectricaldoublelayerparametersfortheadsorptionofneutralmoleculesattheelectrodesolutioninterface |
| _version_ |
1807319440114581504 |