Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry.
Birefringence in the mesophase of 4-cyano-4′-n-pentylbiphenyl (5CB) was measured directly under a magnetic field (1200 and 2000 gauss) as a function of temperature with field parallel and perpendicular to the optical axis. Electrical dinole moments of 5CB and benzonitrile were calculated with the Me...
Guardado en:
Autores principales: | , |
---|---|
Formato: | JOUR |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01677322_v44_n1_p63_LopezIqlesias |
Aporte de: |
id |
todo:paper_01677322_v44_n1_p63_LopezIqlesias |
---|---|
record_format |
dspace |
spelling |
todo:paper_01677322_v44_n1_p63_LopezIqlesias2023-10-03T15:05:18Z Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. López Iqlesias, M.C. Barón, M. Birefringence in the mesophase of 4-cyano-4′-n-pentylbiphenyl (5CB) was measured directly under a magnetic field (1200 and 2000 gauss) as a function of temperature with field parallel and perpendicular to the optical axis. Electrical dinole moments of 5CB and benzonitrile were calculated with the Mechetti-Barón equations from measurements at three temperatures. Molecular geometries were examined with a semiempirical procedure (AMPAC). The results suqgest that thermal stirring and internal rotations appear to overcome orientational effects of the applied field. © 1989. Fil:Barón, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01677322_v44_n1_p63_LopezIqlesias |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
Birefringence in the mesophase of 4-cyano-4′-n-pentylbiphenyl (5CB) was measured directly under a magnetic field (1200 and 2000 gauss) as a function of temperature with field parallel and perpendicular to the optical axis. Electrical dinole moments of 5CB and benzonitrile were calculated with the Mechetti-Barón equations from measurements at three temperatures. Molecular geometries were examined with a semiempirical procedure (AMPAC). The results suqgest that thermal stirring and internal rotations appear to overcome orientational effects of the applied field. © 1989. |
format |
JOUR |
author |
López Iqlesias, M.C. Barón, M. |
spellingShingle |
López Iqlesias, M.C. Barón, M. Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
author_facet |
López Iqlesias, M.C. Barón, M. |
author_sort |
López Iqlesias, M.C. |
title |
Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
title_short |
Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
title_full |
Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
title_fullStr |
Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
title_full_unstemmed |
Liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
title_sort |
liquid crystal birefringence and electric dipole moment relationship with temperature, weak magnetic field and molecular geometry. |
url |
http://hdl.handle.net/20.500.12110/paper_01677322_v44_n1_p63_LopezIqlesias |
work_keys_str_mv |
AT lopeziqlesiasmc liquidcrystalbirefringenceandelectricdipolemomentrelationshipwithtemperatureweakmagneticfieldandmoleculargeometry AT baronm liquidcrystalbirefringenceandelectricdipolemomentrelationshipwithtemperatureweakmagneticfieldandmoleculargeometry |
_version_ |
1782026069935652864 |