Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide
Three commercial polybutadiene rubber (BR) compounds (high cis, medium cis and high vinyl content) were vulcanized at 433 K, using different amounts of dicumyl peroxide (DCP) as curing agent. To analyze the structural changes produced by the vulcanization process of the three BR isomers, different e...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01429418_v52_n_p117_RodriguezGarraza |
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todo:paper_01429418_v52_n_p117_RodriguezGarraza2023-10-03T14:59:10Z Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide Rodríguez Garraza, A.L. Mansilla, M.A. Depaoli, E.L. Macchi, C. Cerveny, S. Marzocca, A.J. Somoza, A. Differential scanning calorimetry Polybutadiene rubber Positron annihilation lifetime spectroscopy Rheometry Swelling Vulcanization Calorimeters Calorimetry Differential scanning calorimetry Glass Isomers Oxidation Peroxides Polybutadienes Positron annihilation spectroscopy Positrons Rheometers Rubber Swelling Temperature Vulcanization Comparative studies Experimental techniques Polybutadiene rubbers Polymer fractions Positron annihilation lifetime spectroscopy Rheometry Torque variations Vulcanization process Glass transition Three commercial polybutadiene rubber (BR) compounds (high cis, medium cis and high vinyl content) were vulcanized at 433 K, using different amounts of dicumyl peroxide (DCP) as curing agent. To analyze the structural changes produced by the vulcanization process of the three BR isomers, different experimental techniques (rheometry, swelling tests, differential scanning calorimetry and positron annihilation lifetime spectroscopy) were used. The evolution of the free nanohole volumes, the glass transition temperatures and the polymer fractions at the maximum degree of swelling as a function of the DCP content in the formulation of the different BR compounds are discussed. A correlation between the glass transition temperature and torque variation and a relationship between the fraction of absorbed solvent and free nanohole volume as a function of the DCP content are also considered. © 2016 Elsevier Ltd. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01429418_v52_n_p117_RodriguezGarraza |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Differential scanning calorimetry Polybutadiene rubber Positron annihilation lifetime spectroscopy Rheometry Swelling Vulcanization Calorimeters Calorimetry Differential scanning calorimetry Glass Isomers Oxidation Peroxides Polybutadienes Positron annihilation spectroscopy Positrons Rheometers Rubber Swelling Temperature Vulcanization Comparative studies Experimental techniques Polybutadiene rubbers Polymer fractions Positron annihilation lifetime spectroscopy Rheometry Torque variations Vulcanization process Glass transition |
| spellingShingle |
Differential scanning calorimetry Polybutadiene rubber Positron annihilation lifetime spectroscopy Rheometry Swelling Vulcanization Calorimeters Calorimetry Differential scanning calorimetry Glass Isomers Oxidation Peroxides Polybutadienes Positron annihilation spectroscopy Positrons Rheometers Rubber Swelling Temperature Vulcanization Comparative studies Experimental techniques Polybutadiene rubbers Polymer fractions Positron annihilation lifetime spectroscopy Rheometry Torque variations Vulcanization process Glass transition Rodríguez Garraza, A.L. Mansilla, M.A. Depaoli, E.L. Macchi, C. Cerveny, S. Marzocca, A.J. Somoza, A. Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| topic_facet |
Differential scanning calorimetry Polybutadiene rubber Positron annihilation lifetime spectroscopy Rheometry Swelling Vulcanization Calorimeters Calorimetry Differential scanning calorimetry Glass Isomers Oxidation Peroxides Polybutadienes Positron annihilation spectroscopy Positrons Rheometers Rubber Swelling Temperature Vulcanization Comparative studies Experimental techniques Polybutadiene rubbers Polymer fractions Positron annihilation lifetime spectroscopy Rheometry Torque variations Vulcanization process Glass transition |
| description |
Three commercial polybutadiene rubber (BR) compounds (high cis, medium cis and high vinyl content) were vulcanized at 433 K, using different amounts of dicumyl peroxide (DCP) as curing agent. To analyze the structural changes produced by the vulcanization process of the three BR isomers, different experimental techniques (rheometry, swelling tests, differential scanning calorimetry and positron annihilation lifetime spectroscopy) were used. The evolution of the free nanohole volumes, the glass transition temperatures and the polymer fractions at the maximum degree of swelling as a function of the DCP content in the formulation of the different BR compounds are discussed. A correlation between the glass transition temperature and torque variation and a relationship between the fraction of absorbed solvent and free nanohole volume as a function of the DCP content are also considered. © 2016 Elsevier Ltd. All rights reserved. |
| format |
JOUR |
| author |
Rodríguez Garraza, A.L. Mansilla, M.A. Depaoli, E.L. Macchi, C. Cerveny, S. Marzocca, A.J. Somoza, A. |
| author_facet |
Rodríguez Garraza, A.L. Mansilla, M.A. Depaoli, E.L. Macchi, C. Cerveny, S. Marzocca, A.J. Somoza, A. |
| author_sort |
Rodríguez Garraza, A.L. |
| title |
Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| title_short |
Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| title_full |
Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| title_fullStr |
Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| title_full_unstemmed |
Comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| title_sort |
comparative study of thermal, mechanical and structural properties of polybutadiene rubber isomers vulcanized using peroxide |
| url |
http://hdl.handle.net/20.500.12110/paper_01429418_v52_n_p117_RodriguezGarraza |
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1807315517442097152 |