Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate

The title complexes, [RuCl(C9H21N3)(C 12H12N2O2)]ClO4· 2C2H3N, (I), and [Ru(C9H 21N3)(C12H12N2O 2)(H2O)](ClO4)2·2H 2O, (II), display similar structures with the Ru atom in a distorted octa-hedral environment. In the crystal packing of the chloride complex, (I), the Ru complex mol-ecules are held tog...

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Detalles Bibliográficos
Autores principales: Vera, D.B., Osa Codesido, N., De Candia, A.G., Alborés, P., Slep, L.D.
Formato: JOUR
Materias:
Aqua complexes
Bipyridine ligands
Bipyridines
Chloride complexes
Chloride ligands
Crystal packings
Dihydrates
Electron-rich
Hydrogen bonded network
Ru complexes
Acetonitrile
Crystal atomic structure
Hydrogen bonds
Inorganic compounds
Ligands
Ruthenium
Ruthenium compounds
Chlorine compounds
Tetra
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v68_n5_pm127_Vera
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The title complexes, [RuCl(C9H21N3)(C 12H12N2O2)]ClO4· 2C2H3N, (I), and [Ru(C9H 21N3)(C12H12N2O 2)(H2O)](ClO4)2·2H 2O, (II), display similar structures with the Ru atom in a distorted octa-hedral environment. In the crystal packing of the chloride complex, (I), the Ru complex mol-ecules are held together in pairs through C - H⋯Cl inter-actions of the 4,4′-dimeth-oxy-2,2′-bipyridine and chloride ligands. In the case of the aqua complex, (II), hydrogen bonding affords a tetra-meric hydrogen-bonded network. These two structures are the first examples of complexes with the {Ru(1,4,7-trimethyl-1,4,7-triaza-cyclo-nona-ne)} motif and an electron-rich substituted 2,2′-bipyridine ligand. © 2012 International Union of Crystallography.

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