Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate

The title complexes, [RuCl(C9H21N3)(C 12H12N2O2)]ClO4· 2C2H3N, (I), and [Ru(C9H 21N3)(C12H12N2O 2)(H2O)](ClO4)2·2H 2O, (II), display similar structures with the Ru atom in a distorted octa-hedral environment. In the crystal packing of the chloride complex, (I), the Ru complex mol-ecules are held tog...

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Autores principales: Vera, D.B., Osa Codesido, N., De Candia, A.G., Alborés, P., Slep, L.D.
Formato: JOUR
Materias:
Aqua complexes
Bipyridine ligands
Bipyridines
Chloride complexes
Chloride ligands
Crystal packings
Dihydrates
Electron-rich
Hydrogen bonded network
Ru complexes
Acetonitrile
Crystal atomic structure
Hydrogen bonds
Inorganic compounds
Ligands
Ruthenium
Ruthenium compounds
Chlorine compounds
Tetra
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v68_n5_pm127_Vera
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_01082701_v68_n5_pm127_Vera2023-10-03T14:57:55Z Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate Vera, D.B. Osa Codesido, N. De Candia, A.G. Alborés, P. Slep, L.D. Aqua complexes Bipyridine ligands Bipyridines Chloride complexes Chloride ligands Crystal packings Dihydrates Electron-rich Hydrogen bonded network Ru complexes Acetonitrile Crystal atomic structure Hydrogen bonds Inorganic compounds Ligands Ruthenium Ruthenium compounds Chlorine compounds Tetra The title complexes, [RuCl(C9H21N3)(C 12H12N2O2)]ClO4· 2C2H3N, (I), and [Ru(C9H 21N3)(C12H12N2O 2)(H2O)](ClO4)2·2H 2O, (II), display similar structures with the Ru atom in a distorted octa-hedral environment. In the crystal packing of the chloride complex, (I), the Ru complex mol-ecules are held together in pairs through C - H⋯Cl inter-actions of the 4,4′-dimeth-oxy-2,2′-bipyridine and chloride ligands. In the case of the aqua complex, (II), hydrogen bonding affords a tetra-meric hydrogen-bonded network. These two structures are the first examples of complexes with the {Ru(1,4,7-trimethyl-1,4,7-triaza-cyclo-nona-ne)} motif and an electron-rich substituted 2,2′-bipyridine ligand. © 2012 International Union of Crystallography. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v68_n5_pm127_Vera
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Aqua complexes
Bipyridine ligands
Bipyridines
Chloride complexes
Chloride ligands
Crystal packings
Dihydrates
Electron-rich
Hydrogen bonded network
Ru complexes
Acetonitrile
Crystal atomic structure
Hydrogen bonds
Inorganic compounds
Ligands
Ruthenium
Ruthenium compounds
Chlorine compounds
Tetra
spellingShingle Aqua complexes
Bipyridine ligands
Bipyridines
Chloride complexes
Chloride ligands
Crystal packings
Dihydrates
Electron-rich
Hydrogen bonded network
Ru complexes
Acetonitrile
Crystal atomic structure
Hydrogen bonds
Inorganic compounds
Ligands
Ruthenium
Ruthenium compounds
Chlorine compounds
Tetra
Vera, D.B.
Osa Codesido, N.
De Candia, A.G.
Alborés, P.
Slep, L.D.
Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
topic_facet Aqua complexes
Bipyridine ligands
Bipyridines
Chloride complexes
Chloride ligands
Crystal packings
Dihydrates
Electron-rich
Hydrogen bonded network
Ru complexes
Acetonitrile
Crystal atomic structure
Hydrogen bonds
Inorganic compounds
Ligands
Ruthenium
Ruthenium compounds
Chlorine compounds
Tetra
description The title complexes, [RuCl(C9H21N3)(C 12H12N2O2)]ClO4· 2C2H3N, (I), and [Ru(C9H 21N3)(C12H12N2O 2)(H2O)](ClO4)2·2H 2O, (II), display similar structures with the Ru atom in a distorted octa-hedral environment. In the crystal packing of the chloride complex, (I), the Ru complex mol-ecules are held together in pairs through C - H⋯Cl inter-actions of the 4,4′-dimeth-oxy-2,2′-bipyridine and chloride ligands. In the case of the aqua complex, (II), hydrogen bonding affords a tetra-meric hydrogen-bonded network. These two structures are the first examples of complexes with the {Ru(1,4,7-trimethyl-1,4,7-triaza-cyclo-nona-ne)} motif and an electron-rich substituted 2,2′-bipyridine ligand. © 2012 International Union of Crystallography.
format JOUR
author Vera, D.B.
Osa Codesido, N.
De Candia, A.G.
Alborés, P.
Slep, L.D.
author_facet Vera, D.B.
Osa Codesido, N.
De Candia, A.G.
Alborés, P.
Slep, L.D.
author_sort Vera, D.B.
title Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
title_short Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
title_full Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
title_fullStr Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
title_full_unstemmed Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
title_sort chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(ii) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(ii) bis-(per-chlorate) dihydrate
url http://hdl.handle.net/20.500.12110/paper_01082701_v68_n5_pm127_Vera
work_keys_str_mv AT veradb chlorido44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiiperchlorateacetonitriledisolvateandaqua44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiibisperchloratedihydrate
AT osacodesidon chlorido44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiiperchlorateacetonitriledisolvateandaqua44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiibisperchloratedihydrate
AT decandiaag chlorido44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiiperchlorateacetonitriledisolvateandaqua44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiibisperchloratedihydrate
AT alboresp chlorido44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiiperchlorateacetonitriledisolvateandaqua44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiibisperchloratedihydrate
AT slepld chlorido44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiiperchlorateacetonitriledisolvateandaqua44dimethoxy22bipyridine147trimethyl147triazacyclononanerutheniumiibisperchloratedihydrate
_version_ 1807323883599036416

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