A new polymeric phase of zinc(II) oxydiacetate
A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presen...
Guardado en:
Autores principales: | , , |
---|---|
Formato: | JOUR |
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio |
Aporte de: |
id |
todo:paper_01082701_v59_n1_pm30_Baggio |
---|---|
record_format |
dspace |
spelling |
todo:paper_01082701_v59_n1_pm30_Baggio2023-10-03T14:57:50Z A new polymeric phase of zinc(II) oxydiacetate Baggio, R. Garland, M.T. Perec, M. Carboxylic acids Crystal structure Crystallography Hydrogen bonds Molecular structure Polymers Zinc compounds Polymeric phases Organometallics Catena A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Carboxylic acids Crystal structure Crystallography Hydrogen bonds Molecular structure Polymers Zinc compounds Polymeric phases Organometallics Catena |
spellingShingle |
Carboxylic acids Crystal structure Crystallography Hydrogen bonds Molecular structure Polymers Zinc compounds Polymeric phases Organometallics Catena Baggio, R. Garland, M.T. Perec, M. A new polymeric phase of zinc(II) oxydiacetate |
topic_facet |
Carboxylic acids Crystal structure Crystallography Hydrogen bonds Molecular structure Polymers Zinc compounds Polymeric phases Organometallics Catena |
description |
A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules. |
format |
JOUR |
author |
Baggio, R. Garland, M.T. Perec, M. |
author_facet |
Baggio, R. Garland, M.T. Perec, M. |
author_sort |
Baggio, R. |
title |
A new polymeric phase of zinc(II) oxydiacetate |
title_short |
A new polymeric phase of zinc(II) oxydiacetate |
title_full |
A new polymeric phase of zinc(II) oxydiacetate |
title_fullStr |
A new polymeric phase of zinc(II) oxydiacetate |
title_full_unstemmed |
A new polymeric phase of zinc(II) oxydiacetate |
title_sort |
new polymeric phase of zinc(ii) oxydiacetate |
url |
http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio |
work_keys_str_mv |
AT baggior anewpolymericphaseofzinciioxydiacetate AT garlandmt anewpolymericphaseofzinciioxydiacetate AT perecm anewpolymericphaseofzinciioxydiacetate AT baggior newpolymericphaseofzinciioxydiacetate AT garlandmt newpolymericphaseofzinciioxydiacetate AT perecm newpolymericphaseofzinciioxydiacetate |
_version_ |
1782029486364033024 |