A new polymeric phase of zinc(II) oxydiacetate

A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presen...

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Autores principales: Baggio, R., Garland, M.T., Perec, M.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio
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spelling todo:paper_01082701_v59_n1_pm30_Baggio2023-10-03T14:57:50Z A new polymeric phase of zinc(II) oxydiacetate Baggio, R. Garland, M.T. Perec, M. Carboxylic acids Crystal structure Crystallography Hydrogen bonds Molecular structure Polymers Zinc compounds Polymeric phases Organometallics Catena A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Carboxylic acids
Crystal structure
Crystallography
Hydrogen bonds
Molecular structure
Polymers
Zinc compounds
Polymeric phases
Organometallics
Catena
spellingShingle Carboxylic acids
Crystal structure
Crystallography
Hydrogen bonds
Molecular structure
Polymers
Zinc compounds
Polymeric phases
Organometallics
Catena
Baggio, R.
Garland, M.T.
Perec, M.
A new polymeric phase of zinc(II) oxydiacetate
topic_facet Carboxylic acids
Crystal structure
Crystallography
Hydrogen bonds
Molecular structure
Polymers
Zinc compounds
Polymeric phases
Organometallics
Catena
description A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules.
format JOUR
author Baggio, R.
Garland, M.T.
Perec, M.
author_facet Baggio, R.
Garland, M.T.
Perec, M.
author_sort Baggio, R.
title A new polymeric phase of zinc(II) oxydiacetate
title_short A new polymeric phase of zinc(II) oxydiacetate
title_full A new polymeric phase of zinc(II) oxydiacetate
title_fullStr A new polymeric phase of zinc(II) oxydiacetate
title_full_unstemmed A new polymeric phase of zinc(II) oxydiacetate
title_sort new polymeric phase of zinc(ii) oxydiacetate
url http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio
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AT perecm anewpolymericphaseofzinciioxydiacetate
AT baggior newpolymericphaseofzinciioxydiacetate
AT garlandmt newpolymericphaseofzinciioxydiacetate
AT perecm newpolymericphaseofzinciioxydiacetate
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