A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate

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The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging...

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Detalles Bibliográficos
Autores principales:	Zelcer, A., Chaia, Z.D., Cukiernik, F.D., Castellano, E.E., Piro, O.E.
Formato:	JOUR
Materias:	Crystal structure Liquid crystals Negative ions Ruthenium compounds X ray diffraction analysis Diruthenium tetradecanoate Long chain carboxylate Organometallics Catena
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_01082701_v58_n3_pm144_Zelcer
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_01082701_v58_n3_pm144_Zelcer
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spelling	todo:paper_01082701_v58_n3_pm144_Zelcer2023-10-03T14:57:49Z A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate Zelcer, A. Chaia, Z.D. Cukiernik, F.D. Castellano, E.E. Piro, O.E. Crystal structure Liquid crystals Negative ions Ruthenium compounds X ray diffraction analysis Diruthenium tetradecanoate Long chain carboxylate Organometallics Catena The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains. Fil:Zelcer, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v58_n3_pm144_Zelcer
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Crystal structure Liquid crystals Negative ions Ruthenium compounds X ray diffraction analysis Diruthenium tetradecanoate Long chain carboxylate Organometallics Catena
spellingShingle	Crystal structure Liquid crystals Negative ions Ruthenium compounds X ray diffraction analysis Diruthenium tetradecanoate Long chain carboxylate Organometallics Catena Zelcer, A. Chaia, Z.D. Cukiernik, F.D. Castellano, E.E. Piro, O.E. A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
topic_facet	Crystal structure Liquid crystals Negative ions Ruthenium compounds X ray diffraction analysis Diruthenium tetradecanoate Long chain carboxylate Organometallics Catena
description	The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
format	JOUR
author	Zelcer, A. Chaia, Z.D. Cukiernik, F.D. Castellano, E.E. Piro, O.E.
author_facet	Zelcer, A. Chaia, Z.D. Cukiernik, F.D. Castellano, E.E. Piro, O.E.
author_sort	Zelcer, A.
title	A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_short	A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_full	A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_fullStr	A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_full_unstemmed	A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate
title_sort	liquid crystal derived from ruthenium(ii, iii) and a long-chain carboxylate
url	http://hdl.handle.net/20.500.12110/paper_01082701_v58_n3_pm144_Zelcer
work_keys_str_mv	AT zelcera aliquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT chaiazd aliquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT cukiernikfd aliquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT castellanoee aliquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT pirooe aliquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT zelcera liquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT chaiazd liquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT cukiernikfd liquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT castellanoee liquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate AT pirooe liquidcrystalderivedfromrutheniumiiiiiandalongchaincarboxylate
_version_	1807317767592869888

A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate

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