Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥

Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu 2(Fasp) 4(MeCN) 2]·2MeCN (1), [Cu 2(Clasp) 4(MeCN) 2]·2MeCN (2), [Cu 2(Brasp) 4 (MeCN) 2]·2MeCN (3), {[Cu 2(Fasp) 4(Pyrz)]·2MeCN} n (4), {[Cu 2(Clasp) 4(Pyrz)]·2MeCN} n (5), [Cu 2(Brasp) 4(Pyrz)] n (6), [Cu 2(Clasp...

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Detalles Bibliográficos
Autores principales:	Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E.
Formato:	JOUR
Materias:	Copper(II) complexes Crystal structures Haloaspirinate anions
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00958972_v65_n13_p2341_Rustoy
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00958972_v65_n13_p2341_Rustoy
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spelling	todo:paper_00958972_v65_n13_p2341_Rustoy2023-10-03T14:56:40Z Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥ Rustoy, E.M. Agotegaray, M. Piro, O.E. Castellano, E.E. Copper(II) complexes Crystal structures Haloaspirinate anions Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu 2(Fasp) 4(MeCN) 2]·2MeCN (1), [Cu 2(Clasp) 4(MeCN) 2]·2MeCN (2), [Cu 2(Brasp) 4 (MeCN) 2]·2MeCN (3), {[Cu 2(Fasp) 4(Pyrz)]·2MeCN} n (4), {[Cu 2(Clasp) 4(Pyrz)]·2MeCN} n (5), [Cu 2(Brasp) 4(Pyrz)] n (6), [Cu 2(Clasp) 4(4,4'-Bipy)] n (7), and [Cu 2(Brasp) 4(4,4'-Bipy)] n (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures. © 2012 Taylor & Francis. Fil:Rustoy, E.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00958972_v65_n13_p2341_Rustoy
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Copper(II) complexes Crystal structures Haloaspirinate anions
spellingShingle	Copper(II) complexes Crystal structures Haloaspirinate anions Rustoy, E.M. Agotegaray, M. Piro, O.E. Castellano, E.E. Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
topic_facet	Copper(II) complexes Crystal structures Haloaspirinate anions
description	Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu 2(Fasp) 4(MeCN) 2]·2MeCN (1), [Cu 2(Clasp) 4(MeCN) 2]·2MeCN (2), [Cu 2(Brasp) 4 (MeCN) 2]·2MeCN (3), {[Cu 2(Fasp) 4(Pyrz)]·2MeCN} n (4), {[Cu 2(Clasp) 4(Pyrz)]·2MeCN} n (5), [Cu 2(Brasp) 4(Pyrz)] n (6), [Cu 2(Clasp) 4(4,4'-Bipy)] n (7), and [Cu 2(Brasp) 4(4,4'-Bipy)] n (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures. © 2012 Taylor & Francis.
format	JOUR
author	Rustoy, E.M. Agotegaray, M. Piro, O.E. Castellano, E.E.
author_facet	Rustoy, E.M. Agotegaray, M. Piro, O.E. Castellano, E.E.
author_sort	Rustoy, E.M.
title	Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
title_short	Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
title_full	Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
title_fullStr	Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
title_full_unstemmed	Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
title_sort	crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(ii)⊥
url	http://hdl.handle.net/20.500.12110/paper_00958972_v65_n13_p2341_Rustoy
work_keys_str_mv	AT rustoyem crystalstructureandspectroscopicpropertiesofpolymericadductsofthetetramhaloaspirinatedicopperii AT agotegaraym crystalstructureandspectroscopicpropertiesofpolymericadductsofthetetramhaloaspirinatedicopperii AT pirooe crystalstructureandspectroscopicpropertiesofpolymericadductsofthetetramhaloaspirinatedicopperii AT castellanoee crystalstructureandspectroscopicpropertiesofpolymericadductsofthetetramhaloaspirinatedicopperii
_version_	1782023685748555776

Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥

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