Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane

A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction.

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Detalles Bibliográficos
Autores principales: Ferrara, A., Burton, G.
Formato: JOUR
Materias:
pregnane derivative
article
drug synthesis
reaction analysis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00404039_v37_n7_p929_Ferrara
record_format dspace
spelling todo:paper_00404039_v37_n7_p929_Ferrara2023-10-03T14:50:51Z Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane Ferrara, A. Burton, G. pregnane derivative article drug synthesis reaction analysis A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction. Fil:Ferrara, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic pregnane derivative
article
drug synthesis
reaction analysis
spellingShingle pregnane derivative
article
drug synthesis
reaction analysis
Ferrara, A.
Burton, G.
Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
topic_facet pregnane derivative
article
drug synthesis
reaction analysis
description A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction.
format JOUR
author Ferrara, A.
Burton, G.
author_facet Ferrara, A.
Burton, G.
author_sort Ferrara, A.
title Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_short Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_full Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_fullStr Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_full_unstemmed Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_sort ring expansion of fused cyclopropylketones. synthesis of a 12(13→18)-abeo-pregnane
url http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
work_keys_str_mv AT ferraraa ringexpansionoffusedcyclopropylketonessynthesisofa121318abeopregnane
AT burtong ringexpansionoffusedcyclopropylketonessynthesisofa121318abeopregnane
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