Synthesis of C-C bonded dimeric steroids by olefin metathesis

Five new C-C bonded steroidal homodimers derived from deoxycholic acid, pregnenolone, and progesterone were synthesized by an olefin metathesis reaction assisted by microwave heating. Microwave improved the yield and accelerated the reaction allowing the use of less catalyst with good results (2.5 m...

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Detalles Bibliográficos
Autores principales:	Edelsztein, V.C., Di Chenna, P.H., Burton, G.
Formato:	JOUR
Materias:	Dimeric steroids Dimerization Metathesis Microwave alkene deoxycholic acid isomerase pregnenolone progesterone steroid article chemical reaction chemical structure dimerization hydrogen bond microwave cooking priority journal ring closing metathesis synthesis
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00404020_v65_n18_p3615_Edelsztein
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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