Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols

The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that t...

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Autores principales: Balsells, R.E., Frasca, A.R.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00404020_v38_n16_p2525_Balsells
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00404020_v38_n16_p2525_Balsells2023-10-03T14:50:32Z Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols Balsells, R.E. Frasca, A.R. The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that the glycols are formed with a stereochemistry very different depending upon whether the substrate is an alcohol or a carbonyl compound. The structure, configuration and conformation of the 1-4-dixoanes obtained are studies as well as their origin. Other aspects of the photochemistry of the alcohols are analyzed using hydroperoxides as model substrates. © 1982. Fil:Frasca, A.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00404020_v38_n16_p2525_Balsells
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that the glycols are formed with a stereochemistry very different depending upon whether the substrate is an alcohol or a carbonyl compound. The structure, configuration and conformation of the 1-4-dixoanes obtained are studies as well as their origin. Other aspects of the photochemistry of the alcohols are analyzed using hydroperoxides as model substrates. © 1982.
format JOUR
author Balsells, R.E.
Frasca, A.R.
spellingShingle Balsells, R.E.
Frasca, A.R.
Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
author_facet Balsells, R.E.
Frasca, A.R.
author_sort Balsells, R.E.
title Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_short Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_full Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_fullStr Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_full_unstemmed Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_sort photochemical reaction of alcohols-ii. irradiation of aromatic alcohols
url http://hdl.handle.net/20.500.12110/paper_00404020_v38_n16_p2525_Balsells
work_keys_str_mv AT balsellsre photochemicalreactionofalcoholsiiirradiationofaromaticalcohols
AT frascaar photochemicalreactionofalcoholsiiirradiationofaromaticalcohols
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