Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3

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The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternativ...

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Detalles Bibliográficos
Autor principal: Gros, E.G.
Formato: JOUR
Materias:
cleavage of epoxides
ring A steroidal elimination
steroidal epoxides
epoxide
lithium chloride
n,n dimethylacetamide
steroid
article
chemical reaction
degradation
ph
proton nuclear magnetic resonance
Cations
Epoxy Compounds
Lithium
Molecular Structure
Solvents
Steroids
Support, Non-U.S. Gov't
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995.

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