Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3
The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternativ...
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todo:paper_0039128X_v60_n7_p434_Gros2023-10-03T14:49:23Z Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 Gros, E.G. cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't |
spellingShingle |
cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't Gros, E.G. Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
topic_facet |
cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't |
description |
The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995. |
format |
JOUR |
author |
Gros, E.G. |
author_facet |
Gros, E.G. |
author_sort |
Gros, E.G. |
title |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
title_short |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
title_full |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
title_fullStr |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
title_full_unstemmed |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
title_sort |
cleavage reaction of 5β,6β steroidal epoxides carrying different groups at c-3 |
url |
http://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros |
work_keys_str_mv |
AT groseg cleavagereactionof5b6bsteroidalepoxidescarryingdifferentgroupsatc3 |
_version_ |
1782027278471921664 |