Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence

We present measurements of the molecular rotational diffusion dynamics in the picosecond scale in a Coumarin 153 ethylene-glycol solution. A novel technique is used in which the fluorescent sample is excited with two femtosecond laser pulses in a pump and probe scheme. The spatial anisotropy generat...

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Autores principales: Torga, J., Marconi, M.C., García-Segundo, C., Villagrán-Muníz, M.
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00304018_v195_n1-4_p215_Torga
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spelling todo:paper_00304018_v195_n1-4_p215_Torga2023-10-03T14:40:07Z Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence Torga, J. Marconi, M.C. García-Segundo, C. Villagrán-Muníz, M. Rotational depolarization Rotational diffusion time Time-resolved fluorescence Fluorescence Molecular dynamics Optical pumping Ultrashort pulses Molecular rotational dynamics Rotational depolarization Ultrafast phenomena We present measurements of the molecular rotational diffusion dynamics in the picosecond scale in a Coumarin 153 ethylene-glycol solution. A novel technique is used in which the fluorescent sample is excited with two femtosecond laser pulses in a pump and probe scheme. The spatial anisotropy generated by the first pulse excitation is sampled as a function of delay time through the fluorescence produced by the delayed pulse. The rotational time is obtained from the change in the fluorescence produced as a function of the delay time. © 2001 Elsevier Science B.V. All rights reserved. Fil:Torga, J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Marconi, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00304018_v195_n1-4_p215_Torga
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Rotational depolarization
Rotational diffusion time
Time-resolved fluorescence
Fluorescence
Molecular dynamics
Optical pumping
Ultrashort pulses
Molecular rotational dynamics
Rotational depolarization
Ultrafast phenomena
spellingShingle Rotational depolarization
Rotational diffusion time
Time-resolved fluorescence
Fluorescence
Molecular dynamics
Optical pumping
Ultrashort pulses
Molecular rotational dynamics
Rotational depolarization
Ultrafast phenomena
Torga, J.
Marconi, M.C.
García-Segundo, C.
Villagrán-Muníz, M.
Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
topic_facet Rotational depolarization
Rotational diffusion time
Time-resolved fluorescence
Fluorescence
Molecular dynamics
Optical pumping
Ultrashort pulses
Molecular rotational dynamics
Rotational depolarization
Ultrafast phenomena
description We present measurements of the molecular rotational diffusion dynamics in the picosecond scale in a Coumarin 153 ethylene-glycol solution. A novel technique is used in which the fluorescent sample is excited with two femtosecond laser pulses in a pump and probe scheme. The spatial anisotropy generated by the first pulse excitation is sampled as a function of delay time through the fluorescence produced by the delayed pulse. The rotational time is obtained from the change in the fluorescence produced as a function of the delay time. © 2001 Elsevier Science B.V. All rights reserved.
format JOUR
author Torga, J.
Marconi, M.C.
García-Segundo, C.
Villagrán-Muníz, M.
author_facet Torga, J.
Marconi, M.C.
García-Segundo, C.
Villagrán-Muníz, M.
author_sort Torga, J.
title Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
title_short Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
title_full Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
title_fullStr Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
title_full_unstemmed Ultra-fast dynamics in Coumarin 153 obtained by differential fluorescence
title_sort ultra-fast dynamics in coumarin 153 obtained by differential fluorescence
url http://hdl.handle.net/20.500.12110/paper_00304018_v195_n1-4_p215_Torga
work_keys_str_mv AT torgaj ultrafastdynamicsincoumarin153obtainedbydifferentialfluorescence
AT marconimc ultrafastdynamicsincoumarin153obtainedbydifferentialfluorescence
AT garciasegundoc ultrafastdynamicsincoumarin153obtainedbydifferentialfluorescence
AT villagranmunizm ultrafastdynamicsincoumarin153obtainedbydifferentialfluorescence
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