Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]

THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosyla...

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Autores principales: Deulofeu, V., Deferrari, J.O.
Formato: JOUR
Lenguaje:English
Materias:
glucose
article
GLUCOSE
Glucose
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00280836_v167_n4236_p42_Deulofeu
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00280836_v167_n4236_p42_Deulofeu
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spelling todo:paper_00280836_v167_n4236_p42_Deulofeu2023-10-03T14:38:26Z Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19] Deulofeu, V. Deferrari, J.O. glucose article GLUCOSE Glucose THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosylamine. The same product resulted from the action of ammonia on penta-acetyl-aldehydo-D-glucose. Later, Niemann and Hays3 prepared N-acetyl-D-glucofuranosylamine by the action of methanolic ammonia on penta-acetyl-D-β-glucose, a reaction that produced the transformation of the original pyranose ring of the acetylated glucose into a furanose structure. © 1951 Nature Publishing Group. Fil:Deulofeu, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR English info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00280836_v167_n4236_p42_Deulofeu
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
language English
orig_language_str_mv English
topic glucose
article
GLUCOSE
Glucose
spellingShingle glucose
article
GLUCOSE
Glucose
Deulofeu, V.
Deferrari, J.O.
Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
topic_facet glucose
article
GLUCOSE
Glucose
description THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosylamine. The same product resulted from the action of ammonia on penta-acetyl-aldehydo-D-glucose. Later, Niemann and Hays3 prepared N-acetyl-D-glucofuranosylamine by the action of methanolic ammonia on penta-acetyl-D-β-glucose, a reaction that produced the transformation of the original pyranose ring of the acetylated glucose into a furanose structure. © 1951 Nature Publishing Group.
format JOUR
author Deulofeu, V.
Deferrari, J.O.
author_facet Deulofeu, V.
Deferrari, J.O.
author_sort Deulofeu, V.
title Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_short Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_full Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_fullStr Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_full_unstemmed Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_sort preparation of d-glucose dibenzamide from pentabenzoyl-d-α-glucose [19]
url http://hdl.handle.net/20.500.12110/paper_00280836_v167_n4236_p42_Deulofeu
work_keys_str_mv AT deulofeuv preparationofdglucosedibenzamidefrompentabenzoyldaglucose19
AT deferrarijo preparationofdglucosedibenzamidefrompentabenzoyldaglucose19
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