R-matrix theory of molecular collisions

The use of Wigner and Eisenbud's R-matrix theory for molecular collisions is discussed. A model of harmonic oscillators is proposed; in this model the activated complex has one negative normal frequency. An example is calculated. The results show that for certain parameters of the potential ene...

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Autor principal: Blum, L.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00268976_v11_n1_p63_Blum
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00268976_v11_n1_p63_Blum2023-10-03T14:37:19Z R-matrix theory of molecular collisions Blum, L. The use of Wigner and Eisenbud's R-matrix theory for molecular collisions is discussed. A model of harmonic oscillators is proposed; in this model the activated complex has one negative normal frequency. An example is calculated. The results show that for certain parameters of the potential energy function the experimental order of magnitude for the steric factor is obtained. When the range of the interacting potential increases, quite narrow Breit-Wigner resonances result. © 1966, Taylor & Francis Group, LLC. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00268976_v11_n1_p63_Blum
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The use of Wigner and Eisenbud's R-matrix theory for molecular collisions is discussed. A model of harmonic oscillators is proposed; in this model the activated complex has one negative normal frequency. An example is calculated. The results show that for certain parameters of the potential energy function the experimental order of magnitude for the steric factor is obtained. When the range of the interacting potential increases, quite narrow Breit-Wigner resonances result. © 1966, Taylor & Francis Group, LLC. All rights reserved.
format JOUR
author Blum, L.
spellingShingle Blum, L.
R-matrix theory of molecular collisions
author_facet Blum, L.
author_sort Blum, L.
title R-matrix theory of molecular collisions
title_short R-matrix theory of molecular collisions
title_full R-matrix theory of molecular collisions
title_fullStr R-matrix theory of molecular collisions
title_full_unstemmed R-matrix theory of molecular collisions
title_sort r-matrix theory of molecular collisions
url http://hdl.handle.net/20.500.12110/paper_00268976_v11_n1_p63_Blum
work_keys_str_mv AT bluml rmatrixtheoryofmolecularcollisions
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