Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH
The effect of adding NaCl or CaCl2 on particle size distribution and flow behaviour of caseinomacropeptide (CMP) aqueous solutions was investigated over a wide range of concentrations (0–200 mmol L−1), temperatures (5–60 °C) and during 14 days of storage. In the absence of salts, CMP mainly presente...
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todo:paper_00236438_v98_n_p598_Loria2023-10-03T14:34:25Z Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH Loria, K.G. Pilosof, A.M.R. Farías, M.E. CaCl2 Caseinomacropeptide Flow behaviour NaCl Salts interactions Self-assembly Calcium chloride Particle size Particle size analysis Size distribution Sodium chloride Solutions Viscosity CaCl2 Caseinomacropeptide Concentrated regime Flow behaviours Hydrophobic association Monomeric forms NaCl Small variations Self assembly The effect of adding NaCl or CaCl2 on particle size distribution and flow behaviour of caseinomacropeptide (CMP) aqueous solutions was investigated over a wide range of concentrations (0–200 mmol L−1), temperatures (5–60 °C) and during 14 days of storage. In the absence of salts, CMP mainly presented a monomeric form at pH 7.0. If sodium or calcium chloride is added, hydrophobic associations of CMP is promoted due to screening of electric charges. Calcium chloride had a bigger impact than NaCl. Indeed, small variations in CaCl2 concentration induced major changes in size distributions and increased the viscosity and the cloudiness of CMP solutions upon storage. The largest aggregates and highest viscosities were obtained at concentrated regime (CMP concentration > 8 g/100 g), high CaCl2 concentration (>1.2 mmol g−1 CMP) and upon storage. © 2018 Elsevier Ltd JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00236438_v98_n_p598_Loria |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
CaCl2 Caseinomacropeptide Flow behaviour NaCl Salts interactions Self-assembly Calcium chloride Particle size Particle size analysis Size distribution Sodium chloride Solutions Viscosity CaCl2 Caseinomacropeptide Concentrated regime Flow behaviours Hydrophobic association Monomeric forms NaCl Small variations Self assembly |
spellingShingle |
CaCl2 Caseinomacropeptide Flow behaviour NaCl Salts interactions Self-assembly Calcium chloride Particle size Particle size analysis Size distribution Sodium chloride Solutions Viscosity CaCl2 Caseinomacropeptide Concentrated regime Flow behaviours Hydrophobic association Monomeric forms NaCl Small variations Self assembly Loria, K.G. Pilosof, A.M.R. Farías, M.E. Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH |
topic_facet |
CaCl2 Caseinomacropeptide Flow behaviour NaCl Salts interactions Self-assembly Calcium chloride Particle size Particle size analysis Size distribution Sodium chloride Solutions Viscosity CaCl2 Caseinomacropeptide Concentrated regime Flow behaviours Hydrophobic association Monomeric forms NaCl Small variations Self assembly |
description |
The effect of adding NaCl or CaCl2 on particle size distribution and flow behaviour of caseinomacropeptide (CMP) aqueous solutions was investigated over a wide range of concentrations (0–200 mmol L−1), temperatures (5–60 °C) and during 14 days of storage. In the absence of salts, CMP mainly presented a monomeric form at pH 7.0. If sodium or calcium chloride is added, hydrophobic associations of CMP is promoted due to screening of electric charges. Calcium chloride had a bigger impact than NaCl. Indeed, small variations in CaCl2 concentration induced major changes in size distributions and increased the viscosity and the cloudiness of CMP solutions upon storage. The largest aggregates and highest viscosities were obtained at concentrated regime (CMP concentration > 8 g/100 g), high CaCl2 concentration (>1.2 mmol g−1 CMP) and upon storage. © 2018 Elsevier Ltd |
format |
JOUR |
author |
Loria, K.G. Pilosof, A.M.R. Farías, M.E. |
author_facet |
Loria, K.G. Pilosof, A.M.R. Farías, M.E. |
author_sort |
Loria, K.G. |
title |
Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH |
title_short |
Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH |
title_full |
Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH |
title_fullStr |
Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH |
title_full_unstemmed |
Influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral pH |
title_sort |
influence of calcium and sodium chloride on caseinomacropeptide self-assembly and flow behaviour at neutral ph |
url |
http://hdl.handle.net/20.500.12110/paper_00236438_v98_n_p598_Loria |
work_keys_str_mv |
AT loriakg influenceofcalciumandsodiumchlorideoncaseinomacropeptideselfassemblyandflowbehaviouratneutralph AT pilosofamr influenceofcalciumandsodiumchlorideoncaseinomacropeptideselfassemblyandflowbehaviouratneutralph AT fariasme influenceofcalciumandsodiumchlorideoncaseinomacropeptideselfassemblyandflowbehaviouratneutralph |
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1782024678812942336 |