Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis

The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopin...

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Autores principales: Barton, D.H.R., Boar, R.B., Widdowson, D.A., Deulofeu, V., Albonico, S.M.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00224952_v_n5_p807_Barton
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spelling todo:paper_00224952_v_n5_p807_Barton2023-10-03T14:33:22Z Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis Barton, D.H.R. Boar, R.B. Widdowson, D.A. Deulofeu, V. Albonico, S.M. alkaloid inorganic salt isoquinoline derivative phenol derivative article biosynthesis chemistry medicinal plant metabolism oxidation reduction reaction Alkaloids Chemistry Isoquinolines Oxidation-Reduction Phenols Plants, Medicinal Salts The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopine, (+)-tembetarine is an inefficient precursor. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00224952_v_n5_p807_Barton
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic alkaloid
inorganic salt
isoquinoline derivative
phenol derivative
article
biosynthesis
chemistry
medicinal plant
metabolism
oxidation reduction reaction
Alkaloids
Chemistry
Isoquinolines
Oxidation-Reduction
Phenols
Plants, Medicinal
Salts
spellingShingle alkaloid
inorganic salt
isoquinoline derivative
phenol derivative
article
biosynthesis
chemistry
medicinal plant
metabolism
oxidation reduction reaction
Alkaloids
Chemistry
Isoquinolines
Oxidation-Reduction
Phenols
Plants, Medicinal
Salts
Barton, D.H.R.
Boar, R.B.
Widdowson, D.A.
Deulofeu, V.
Albonico, S.M.
Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
topic_facet alkaloid
inorganic salt
isoquinoline derivative
phenol derivative
article
biosynthesis
chemistry
medicinal plant
metabolism
oxidation reduction reaction
Alkaloids
Chemistry
Isoquinolines
Oxidation-Reduction
Phenols
Plants, Medicinal
Salts
description The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopine, (+)-tembetarine is an inefficient precursor.
format JOUR
author Barton, D.H.R.
Boar, R.B.
Widdowson, D.A.
Deulofeu, V.
Albonico, S.M.
author_facet Barton, D.H.R.
Boar, R.B.
Widdowson, D.A.
Deulofeu, V.
Albonico, S.M.
author_sort Barton, D.H.R.
title Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
title_short Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
title_full Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
title_fullStr Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
title_full_unstemmed Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
title_sort phenol oxidation and biosynthesis. part xix. on the role of quaternary metho-salts in alkaloid biosynthesis
url http://hdl.handle.net/20.500.12110/paper_00224952_v_n5_p807_Barton
work_keys_str_mv AT bartondhr phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis
AT boarrb phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis
AT widdowsonda phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis
AT deulofeuv phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis
AT albonicosm phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis
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