Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis
The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopin...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00224952_v_n5_p807_Barton |
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todo:paper_00224952_v_n5_p807_Barton2023-10-03T14:33:22Z Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis Barton, D.H.R. Boar, R.B. Widdowson, D.A. Deulofeu, V. Albonico, S.M. alkaloid inorganic salt isoquinoline derivative phenol derivative article biosynthesis chemistry medicinal plant metabolism oxidation reduction reaction Alkaloids Chemistry Isoquinolines Oxidation-Reduction Phenols Plants, Medicinal Salts The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopine, (+)-tembetarine is an inefficient precursor. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00224952_v_n5_p807_Barton |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
alkaloid inorganic salt isoquinoline derivative phenol derivative article biosynthesis chemistry medicinal plant metabolism oxidation reduction reaction Alkaloids Chemistry Isoquinolines Oxidation-Reduction Phenols Plants, Medicinal Salts |
spellingShingle |
alkaloid inorganic salt isoquinoline derivative phenol derivative article biosynthesis chemistry medicinal plant metabolism oxidation reduction reaction Alkaloids Chemistry Isoquinolines Oxidation-Reduction Phenols Plants, Medicinal Salts Barton, D.H.R. Boar, R.B. Widdowson, D.A. Deulofeu, V. Albonico, S.M. Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis |
topic_facet |
alkaloid inorganic salt isoquinoline derivative phenol derivative article biosynthesis chemistry medicinal plant metabolism oxidation reduction reaction Alkaloids Chemistry Isoquinolines Oxidation-Reduction Phenols Plants, Medicinal Salts |
description |
The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopine, (+)-tembetarine is an inefficient precursor. |
format |
JOUR |
author |
Barton, D.H.R. Boar, R.B. Widdowson, D.A. Deulofeu, V. Albonico, S.M. |
author_facet |
Barton, D.H.R. Boar, R.B. Widdowson, D.A. Deulofeu, V. Albonico, S.M. |
author_sort |
Barton, D.H.R. |
title |
Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis |
title_short |
Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis |
title_full |
Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis |
title_fullStr |
Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis |
title_full_unstemmed |
Phenol oxidation and biosynthesis. Part XIX. on the role of quaternary metho-salts in alkaloid biosynthesis |
title_sort |
phenol oxidation and biosynthesis. part xix. on the role of quaternary metho-salts in alkaloid biosynthesis |
url |
http://hdl.handle.net/20.500.12110/paper_00224952_v_n5_p807_Barton |
work_keys_str_mv |
AT bartondhr phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis AT boarrb phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis AT widdowsonda phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis AT deulofeuv phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis AT albonicosm phenoloxidationandbiosynthesispartxixontheroleofquaternarymethosaltsinalkaloidbiosynthesis |
_version_ |
1807320381167501312 |