Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)

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The synthesis and the crystal and molecular structures of three metal(II) derivatives of lutidinic acid are presented (lutidinic acid = 2,4-pyridinedicarboxylic acid = H22,4-pydc). Zn(2,4-pydc)(H2O)4]·H2O crystallizes in the monoclinic space group P21/c, with a = 7.764(3), b = 6.546(3), c = 22.021(8...

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Autores principales:	Sileo, E.E., De Araujo, A.S., Rigotti, G., Piro, O.E., Castellano, E.E.
Formato:	JOUR
Materias:	2,4-pyridinedicarboxylate Crystal structure Lutidinate Nickel Zinc 2,4 pyridinedicarboxylic acid coordination compound nickel complex oxygen pyridinedicarboxylic acid unclassified drug zinc complex article chemical binding crystal structure crystallization isomer stereochemistry structure analysis
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00222860_v644_n1-3_p67_Sileo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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spelling	todo:paper_00222860_v644_n1-3_p67_Sileo2023-10-03T14:30:40Z Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic) Sileo, E.E. De Araujo, A.S. Rigotti, G. Piro, O.E. Castellano, E.E. 2,4-pyridinedicarboxylate Crystal structure Lutidinate Nickel Zinc 2,4 pyridinedicarboxylic acid coordination compound nickel complex oxygen pyridinedicarboxylic acid unclassified drug zinc complex article chemical binding crystal structure crystallization isomer stereochemistry structure analysis The synthesis and the crystal and molecular structures of three metal(II) derivatives of lutidinic acid are presented (lutidinic acid = 2,4-pyridinedicarboxylic acid = H22,4-pydc). Zn(2,4-pydc)(H2O)4]·H2O crystallizes in the monoclinic space group P21/c, with a = 7.764(3), b = 6.546(3), c = 22.021(8) Å, β = 91.45(4)°; and Z = 4. Na2[Zn(2,4-pydc)2(H2- O)2]·8H2O crystallizes in P21/a, with a = 7.070(2), b = 13.630(2), c = 12.520(1) Å; β = 91.66(1)°; and Z = 2. [Ni(H2O)6][Ni(2,4-pydc)2 (H2O)2] crystallizes in the triclinic space group P - 1, with a = 5.200(7), b = 7.890(3), c = 13.872(5) Å; a = 84.96(3), β = 85.64(2)°, γ = 73.21(4); and Z = 2. The Zn and Ni ions are hexacoordinated and the lutidinate group is almost planar binding the metal through an oxygen atom from the 2-carboxylate group. All compounds present a dangling uncoordinated 4-carboxylate group. The stereochemistry of the title compounds is compared with other metal (II) pyridinedicarboxylates. © 2002 Elsevier Science B.V. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00222860_v644_n1-3_p67_Sileo
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	2,4-pyridinedicarboxylate Crystal structure Lutidinate Nickel Zinc 2,4 pyridinedicarboxylic acid coordination compound nickel complex oxygen pyridinedicarboxylic acid unclassified drug zinc complex article chemical binding crystal structure crystallization isomer stereochemistry structure analysis
spellingShingle	2,4-pyridinedicarboxylate Crystal structure Lutidinate Nickel Zinc 2,4 pyridinedicarboxylic acid coordination compound nickel complex oxygen pyridinedicarboxylic acid unclassified drug zinc complex article chemical binding crystal structure crystallization isomer stereochemistry structure analysis Sileo, E.E. De Araujo, A.S. Rigotti, G. Piro, O.E. Castellano, E.E. Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
topic_facet	2,4-pyridinedicarboxylate Crystal structure Lutidinate Nickel Zinc 2,4 pyridinedicarboxylic acid coordination compound nickel complex oxygen pyridinedicarboxylic acid unclassified drug zinc complex article chemical binding crystal structure crystallization isomer stereochemistry structure analysis
description	The synthesis and the crystal and molecular structures of three metal(II) derivatives of lutidinic acid are presented (lutidinic acid = 2,4-pyridinedicarboxylic acid = H22,4-pydc). Zn(2,4-pydc)(H2O)4]·H2O crystallizes in the monoclinic space group P21/c, with a = 7.764(3), b = 6.546(3), c = 22.021(8) Å, β = 91.45(4)°; and Z = 4. Na2[Zn(2,4-pydc)2(H2- O)2]·8H2O crystallizes in P21/a, with a = 7.070(2), b = 13.630(2), c = 12.520(1) Å; β = 91.66(1)°; and Z = 2. [Ni(H2O)6][Ni(2,4-pydc)2 (H2O)2] crystallizes in the triclinic space group P - 1, with a = 5.200(7), b = 7.890(3), c = 13.872(5) Å; a = 84.96(3), β = 85.64(2)°, γ = 73.21(4); and Z = 2. The Zn and Ni ions are hexacoordinated and the lutidinate group is almost planar binding the metal through an oxygen atom from the 2-carboxylate group. All compounds present a dangling uncoordinated 4-carboxylate group. The stereochemistry of the title compounds is compared with other metal (II) pyridinedicarboxylates. © 2002 Elsevier Science B.V. All rights reserved.
format	JOUR
author	Sileo, E.E. De Araujo, A.S. Rigotti, G. Piro, O.E. Castellano, E.E.
author_facet	Sileo, E.E. De Araujo, A.S. Rigotti, G. Piro, O.E. Castellano, E.E.
author_sort	Sileo, E.E.
title	Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
title_short	Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
title_full	Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
title_fullStr	Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
title_full_unstemmed	Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
title_sort	solid state coordination chemistry of pyridinedicarboxylic acid isomers. iii synthesis and crystal structures of complexes of zn and ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
url	http://hdl.handle.net/20.500.12110/paper_00222860_v644_n1-3_p67_Sileo
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Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)

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