Specific adsorption of azide on mercury electrodes
The adsorption of azide ion on a mercury electrode in aqueous solution was studied by measuring electrocapillary and capacity curves. The results can be expressed in the form of a simple adsorption isotherm which enables the calculation for the first time of reliable values of the inner Helmholtz po...
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| Autores principales: | , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00220728_v32_n1_p57_DAlkaine |
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| Sumario: | The adsorption of azide ion on a mercury electrode in aqueous solution was studied by measuring electrocapillary and capacity curves. The results can be expressed in the form of a simple adsorption isotherm which enables the calculation for the first time of reliable values of the inner Helmholtz potential (1) and Stern's specific adsorption potential. Experimental values of Levine's self-atmosphere potential parameter (g) are also obtained. © 1971 Elsevier Sequoia S.A., Lausanne. |
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