Volumetric properties of (4-methylphenol + NaOH) at high temperatures

The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methy...

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Autores principales:	Kukuljan, J.A., Méndez De Leo, L.P., Alvarez, J.L., Bianchi, H.L., Fernández-Prini, R.J.
Formato:	JOUR
Materias:	4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Thermodynamics
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00219614_v35_n9_p1541_Kukuljan
record_format	dspace
spelling	todo:paper_00219614_v35_n9_p1541_Kukuljan2023-10-03T14:24:54Z Volumetric properties of (4-methylphenol + NaOH) at high temperatures Kukuljan, J.A. Méndez De Leo, L.P. Alvarez, J.L. Bianchi, H.L. Fernández-Prini, R.J. 4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data. Fil:Méndez De Leo, L.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bianchi, H.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernández-Prini, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics
spellingShingle	4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics Kukuljan, J.A. Méndez De Leo, L.P. Alvarez, J.L. Bianchi, H.L. Fernández-Prini, R.J. Volumetric properties of (4-methylphenol + NaOH) at high temperatures
topic_facet	4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics
description	The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data.
format	JOUR
author	Kukuljan, J.A. Méndez De Leo, L.P. Alvarez, J.L. Bianchi, H.L. Fernández-Prini, R.J.
author_facet	Kukuljan, J.A. Méndez De Leo, L.P. Alvarez, J.L. Bianchi, H.L. Fernández-Prini, R.J.
author_sort	Kukuljan, J.A.
title	Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_short	Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_full	Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_fullStr	Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_full_unstemmed	Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_sort	volumetric properties of (4-methylphenol + naoh) at high temperatures
url	http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan
work_keys_str_mv	AT kukuljanja volumetricpropertiesof4methylphenolnaohathightemperatures AT mendezdeleolp volumetricpropertiesof4methylphenolnaohathightemperatures AT alvarezjl volumetricpropertiesof4methylphenolnaohathightemperatures AT bianchihl volumetricpropertiesof4methylphenolnaohathightemperatures AT fernandezprinirj volumetricpropertiesof4methylphenolnaohathightemperatures
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Volumetric properties of (4-methylphenol + NaOH) at high temperatures

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