Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6

The solubility of I2(S) in supercritical xenon with and without added C6H6 has been measured at the temperatures T = (300.79 ± 0.04) K and (318.70 ± 0.02) K over the pressure range from 5MPa to 10MPa. The u.v. absorbance due to the charge transfer interaction between I2 (acceptor) and C6H6 (donor) w...

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Autores principales: Destaillats, H., Fernández-Prini, R.
Formato: JOUR
Materias:
Charge transfer
Iodine
Solubility
Supercritical fluid
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00219614_v29_n11_p1209_Destaillats
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00219614_v29_n11_p1209_Destaillats2023-10-03T14:24:53Z Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6 Destaillats, H. Fernández-Prini, R. Charge transfer Iodine Solubility Supercritical fluid The solubility of I2(S) in supercritical xenon with and without added C6H6 has been measured at the temperatures T = (300.79 ± 0.04) K and (318.70 ± 0.02) K over the pressure range from 5MPa to 10MPa. The u.v. absorbance due to the charge transfer interaction between I2 (acceptor) and C6H6 (donor) was also measured when the fluid was saturated, and also when unsaturated, with I2. The enhancement of the solubility of I2(s) due to added C6H6 was moderate, supporting the view that the charge transfer process does not contribute significantly to the thermodynamic properties of donor and acceptor. The effect of density on the equilibrium concentration quotient for the formation of the donor-acceptor complex is discussed. © 1997 Academic Press Limited. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00219614_v29_n11_p1209_Destaillats
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Charge transfer
Iodine
Solubility
Supercritical fluid
spellingShingle Charge transfer
Iodine
Solubility
Supercritical fluid
Destaillats, H.
Fernández-Prini, R.
Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6
topic_facet Charge transfer
Iodine
Solubility
Supercritical fluid
description The solubility of I2(S) in supercritical xenon with and without added C6H6 has been measured at the temperatures T = (300.79 ± 0.04) K and (318.70 ± 0.02) K over the pressure range from 5MPa to 10MPa. The u.v. absorbance due to the charge transfer interaction between I2 (acceptor) and C6H6 (donor) was also measured when the fluid was saturated, and also when unsaturated, with I2. The enhancement of the solubility of I2(s) due to added C6H6 was moderate, supporting the view that the charge transfer process does not contribute significantly to the thermodynamic properties of donor and acceptor. The effect of density on the equilibrium concentration quotient for the formation of the donor-acceptor complex is discussed. © 1997 Academic Press Limited.
format JOUR
author Destaillats, H.
Fernández-Prini, R.
author_facet Destaillats, H.
Fernández-Prini, R.
author_sort Destaillats, H.
title Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6
title_short Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6
title_full Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6
title_fullStr Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6
title_full_unstemmed Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6
title_sort solubility of i2(s) and equilibrium concentration of the (i2 + c6h6) charge transfer complex in supercritical xenon with added c6h6
url http://hdl.handle.net/20.500.12110/paper_00219614_v29_n11_p1209_Destaillats
work_keys_str_mv AT destaillatsh solubilityofi2sandequilibriumconcentrationofthei2c6h6chargetransfercomplexinsupercriticalxenonwithaddedc6h6
AT fernandezprinir solubilityofi2sandequilibriumconcentrationofthei2c6h6chargetransfercomplexinsupercriticalxenonwithaddedc6h6
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