X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes
Three new metal-organic coordination complexes have been prepared and their crystal structures determined: [Ni(oda)(H2O)3]·1.5H2O, [Ni(oda)(phen)(H2O)]·1.5H2O and [Ni(oda)(terpy)]·2H2O (oda = oxydiacetate, phen = 1,10-phenanthroline, terpy = 2,2':6',2'' terpyridine). The oxydiace...
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todo:paper_00201693_v310_n1_p103_Baggio2023-10-03T14:17:16Z X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes Baggio, R. Garland, M.T. Perec, M. Crystal structures Nickel adducts Nickel complexes Oxydiacetate complexes 1,10 phenanthroline 2,2':6'2'' terpyridine coordination compound nickel complex nickel oxydiacetate pyridine derivative unclassified drug article crystal structure hydrogen bond molecular interaction synthesis X ray crystallography Three new metal-organic coordination complexes have been prepared and their crystal structures determined: [Ni(oda)(H2O)3]·1.5H2O, [Ni(oda)(phen)(H2O)]·1.5H2O and [Ni(oda)(terpy)]·2H2O (oda = oxydiacetate, phen = 1,10-phenanthroline, terpy = 2,2':6',2'' terpyridine). The oxydiacetate ligand is tridentate in these compounds, being hinged in the first and nearly planar in the other two. Hydrogen-bonding and π-π interaction is extensive in the solids. (C) 2000 Elsevier Science B.V. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v310_n1_p103_Baggio |
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Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Crystal structures Nickel adducts Nickel complexes Oxydiacetate complexes 1,10 phenanthroline 2,2':6'2'' terpyridine coordination compound nickel complex nickel oxydiacetate pyridine derivative unclassified drug article crystal structure hydrogen bond molecular interaction synthesis X ray crystallography |
spellingShingle |
Crystal structures Nickel adducts Nickel complexes Oxydiacetate complexes 1,10 phenanthroline 2,2':6'2'' terpyridine coordination compound nickel complex nickel oxydiacetate pyridine derivative unclassified drug article crystal structure hydrogen bond molecular interaction synthesis X ray crystallography Baggio, R. Garland, M.T. Perec, M. X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
topic_facet |
Crystal structures Nickel adducts Nickel complexes Oxydiacetate complexes 1,10 phenanthroline 2,2':6'2'' terpyridine coordination compound nickel complex nickel oxydiacetate pyridine derivative unclassified drug article crystal structure hydrogen bond molecular interaction synthesis X ray crystallography |
description |
Three new metal-organic coordination complexes have been prepared and their crystal structures determined: [Ni(oda)(H2O)3]·1.5H2O, [Ni(oda)(phen)(H2O)]·1.5H2O and [Ni(oda)(terpy)]·2H2O (oda = oxydiacetate, phen = 1,10-phenanthroline, terpy = 2,2':6',2'' terpyridine). The oxydiacetate ligand is tridentate in these compounds, being hinged in the first and nearly planar in the other two. Hydrogen-bonding and π-π interaction is extensive in the solids. (C) 2000 Elsevier Science B.V. |
format |
JOUR |
author |
Baggio, R. Garland, M.T. Perec, M. |
author_facet |
Baggio, R. Garland, M.T. Perec, M. |
author_sort |
Baggio, R. |
title |
X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
title_short |
X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
title_full |
X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
title_fullStr |
X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
title_full_unstemmed |
X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
title_sort |
x-ray study on the nickel(ii)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes |
url |
http://hdl.handle.net/20.500.12110/paper_00201693_v310_n1_p103_Baggio |
work_keys_str_mv |
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1807319288412897280 |