Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)

The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the...

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Detalles Bibliográficos
Autores principales:	Baggio, R., Garland, M.T., Perec, M., Vega, D.
Formato:	JOUR
Materias:	Cadmium complexes Crystal structures Oxydiacetate complexes Zinc complexes
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201693_v284_n1_p49_Baggio
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00201693_v284_n1_p49_Baggio
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spelling	todo:paper_00201693_v284_n1_p49_Baggio2023-10-03T14:17:14Z Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate) Baggio, R. Garland, M.T. Perec, M. Vega, D. Cadmium complexes Crystal structures Oxydiacetate complexes Zinc complexes The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the carboxylate groups of extended oda ligands; 2 is tetranuclear with the cadmium atoms in pentagonal bipyramidal CdN2O5 coordination geometry. The extended structures and the hydrogen-bonding patterns displayed by both the compounds were examined. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v284_n1_p49_Baggio
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Cadmium complexes Crystal structures Oxydiacetate complexes Zinc complexes
spellingShingle	Cadmium complexes Crystal structures Oxydiacetate complexes Zinc complexes Baggio, R. Garland, M.T. Perec, M. Vega, D. Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
topic_facet	Cadmium complexes Crystal structures Oxydiacetate complexes Zinc complexes
description	The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the carboxylate groups of extended oda ligands; 2 is tetranuclear with the cadmium atoms in pentagonal bipyramidal CdN2O5 coordination geometry. The extended structures and the hydrogen-bonding patterns displayed by both the compounds were examined.
format	JOUR
author	Baggio, R. Garland, M.T. Perec, M. Vega, D.
author_facet	Baggio, R. Garland, M.T. Perec, M. Vega, D.
author_sort	Baggio, R.
title	Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_short	Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_full	Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_fullStr	Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_full_unstemmed	Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
title_sort	adduct formation between zinc and cadmium oxydiacetates and imidazol. crystal structures of [zn(him)2(oda)]n and [cd2(him)4(oda)2(h2o)] 2·6h2o (him=imidazol, oda=oxydiacetate)
url	http://hdl.handle.net/20.500.12110/paper_00201693_v284_n1_p49_Baggio
work_keys_str_mv	AT baggior adductformationbetweenzincandcadmiumoxydiacetatesandimidazolcrystalstructuresofznhim2odanandcd2him4oda2h2o26h2ohimimidazolodaoxydiacetate AT garlandmt adductformationbetweenzincandcadmiumoxydiacetatesandimidazolcrystalstructuresofznhim2odanandcd2him4oda2h2o26h2ohimimidazolodaoxydiacetate AT perecm adductformationbetweenzincandcadmiumoxydiacetatesandimidazolcrystalstructuresofznhim2odanandcd2him4oda2h2o26h2ohimimidazolodaoxydiacetate AT vegad adductformationbetweenzincandcadmiumoxydiacetatesandimidazolcrystalstructuresofznhim2odanandcd2him4oda2h2o26h2ohimimidazolodaoxydiacetate
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Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)

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