Redox potential determines the reaction mechanism of HNO donors with Mn and Fe porphyrins: Defining the better traps

Azanone (1HNO, nitroxyl) is a highly reactive molecule with interesting chemical and biological properties. Like nitric oxide (NO), its main biologically related targets are oxygen, thiols, and metalloproteins, particularly heme proteins. As HNO dimerizes with a rate constant between 106 and 107 M-1...

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Detalles Bibliográficos
Autores principales:	Álvarez, L., Suarez, S.A., Bikiel, D.E., Reboucas, J.S., Batinić-Haberle, I., Martí, M.A., Doctorovich, F.
Formato:	JOUR
Materias:	iron manganese nitrogen oxide nitroxyl porphyrin chemistry kinetics oxidation reduction reaction Iron Kinetics Manganese Nitrogen Oxides Oxidation-Reduction Porphyrins
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201669_v53_n14_p7351_Alvarez
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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