Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines

The synthesis and characterization of a series of ruthenium bis(bipyridine) complexes where the inorganic moiety acts as a photolabile protecting group is described. Complexes of the type [Ru(bpy)2L2]+ where bpy = 2,2′-bipyridine and L = butylamine, γ-aminobutyric acid, tyramine, tryptamine, and ser...

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Autores principales:	Zayat, L., Salierno, M., Etchenique, R.
Formato:	JOUR
Materias:	2,2' bipyridine agents interacting with transmitter, hormone or drug receptors biogenic amine ruthenium derivative article chemistry nuclear magnetic resonance spectroscopy 2,2'-Dipyridyl Biogenic Amines Magnetic Resonance Spectroscopy Neurotransmitter Agents Ruthenium Compounds
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201669_v45_n4_p1728_Zayat
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00201669_v45_n4_p1728_Zayat
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spelling	todo:paper_00201669_v45_n4_p1728_Zayat2023-10-03T14:16:57Z Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines Zayat, L. Salierno, M. Etchenique, R. 2,2' bipyridine agents interacting with transmitter, hormone or drug receptors biogenic amine ruthenium derivative article chemistry nuclear magnetic resonance spectroscopy 2,2'-Dipyridyl Biogenic Amines Magnetic Resonance Spectroscopy Neurotransmitter Agents Ruthenium Compounds The synthesis and characterization of a series of ruthenium bis(bipyridine) complexes where the inorganic moiety acts as a photolabile protecting group is described. Complexes of the type [Ru(bpy)2L2]+ where bpy = 2,2′-bipyridine and L = butylamine, γ-aminobutyric acid, tyramine, tryptamine, and serotonin were studied by nuclear magnetic resonance, cyclic voltammetry, and electronic absorption spectroscopy. In all cases, ligands are coordinated by the amine group. The complexes are stable in water for several days and deliver one molecule of ligand upon irradiation with visible light (450 nm). These properties make them suitable for their use as biological caged compounds. © 2006 American Chemical Society. Fil:Zayat, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Salierno, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Etchenique, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201669_v45_n4_p1728_Zayat
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	2,2' bipyridine agents interacting with transmitter, hormone or drug receptors biogenic amine ruthenium derivative article chemistry nuclear magnetic resonance spectroscopy 2,2'-Dipyridyl Biogenic Amines Magnetic Resonance Spectroscopy Neurotransmitter Agents Ruthenium Compounds
spellingShingle	2,2' bipyridine agents interacting with transmitter, hormone or drug receptors biogenic amine ruthenium derivative article chemistry nuclear magnetic resonance spectroscopy 2,2'-Dipyridyl Biogenic Amines Magnetic Resonance Spectroscopy Neurotransmitter Agents Ruthenium Compounds Zayat, L. Salierno, M. Etchenique, R. Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines
topic_facet	2,2' bipyridine agents interacting with transmitter, hormone or drug receptors biogenic amine ruthenium derivative article chemistry nuclear magnetic resonance spectroscopy 2,2'-Dipyridyl Biogenic Amines Magnetic Resonance Spectroscopy Neurotransmitter Agents Ruthenium Compounds
description	The synthesis and characterization of a series of ruthenium bis(bipyridine) complexes where the inorganic moiety acts as a photolabile protecting group is described. Complexes of the type [Ru(bpy)2L2]+ where bpy = 2,2′-bipyridine and L = butylamine, γ-aminobutyric acid, tyramine, tryptamine, and serotonin were studied by nuclear magnetic resonance, cyclic voltammetry, and electronic absorption spectroscopy. In all cases, ligands are coordinated by the amine group. The complexes are stable in water for several days and deliver one molecule of ligand upon irradiation with visible light (450 nm). These properties make them suitable for their use as biological caged compounds. © 2006 American Chemical Society.
format	JOUR
author	Zayat, L. Salierno, M. Etchenique, R.
author_facet	Zayat, L. Salierno, M. Etchenique, R.
author_sort	Zayat, L.
title	Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines
title_short	Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines
title_full	Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines
title_fullStr	Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines
title_full_unstemmed	Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines
title_sort	ruthenium(ii) bipyridyl complexes as photolabile caging groups for amines
url	http://hdl.handle.net/20.500.12110/paper_00201669_v45_n4_p1728_Zayat
work_keys_str_mv	AT zayatl rutheniumiibipyridylcomplexesasphotolabilecaginggroupsforamines AT saliernom rutheniumiibipyridylcomplexesasphotolabilecaginggroupsforamines AT etcheniquer rutheniumiibipyridylcomplexesasphotolabilecaginggroupsforamines
_version_	1807317820051030016

Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines

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