The carbonylaiion of organolithium compounds: a polar or a radical mechanism?
A variety of riethods were utilized to study the mechanism of carbonylation of organolithium compounds. Convincing evidence that the reaction of aryllithium compounds takes place by radical pathways, being the electron transfer from aryllithium to CO the first rate-determining step, is presented. On...
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00165603_v126_n1_p19_Nudelman |
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todo:paper_00165603_v126_n1_p19_Nudelman2023-10-03T14:13:58Z The carbonylaiion of organolithium compounds: a polar or a radical mechanism? Nudelman, N.S. Doctorovich, F. Linares, G.G. Schulz, H. Mendiara, S. A variety of riethods were utilized to study the mechanism of carbonylation of organolithium compounds. Convincing evidence that the reaction of aryllithium compounds takes place by radical pathways, being the electron transfer from aryllithium to CO the first rate-determining step, is presented. On the other hand, in the rt actions of lithium dialkylamides no evidence for radical intermediates was found. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00165603_v126_n1_p19_Nudelman |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
A variety of riethods were utilized to study the mechanism of carbonylation of organolithium compounds. Convincing evidence that the reaction of aryllithium compounds takes place by radical pathways, being the electron transfer from aryllithium to CO the first rate-determining step, is presented. On the other hand, in the rt actions of lithium dialkylamides no evidence for radical intermediates was found. |
| format |
JOUR |
| author |
Nudelman, N.S. Doctorovich, F. Linares, G.G. Schulz, H. Mendiara, S. |
| spellingShingle |
Nudelman, N.S. Doctorovich, F. Linares, G.G. Schulz, H. Mendiara, S. The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| author_facet |
Nudelman, N.S. Doctorovich, F. Linares, G.G. Schulz, H. Mendiara, S. |
| author_sort |
Nudelman, N.S. |
| title |
The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| title_short |
The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| title_full |
The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| title_fullStr |
The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| title_full_unstemmed |
The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| title_sort |
carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| url |
http://hdl.handle.net/20.500.12110/paper_00165603_v126_n1_p19_Nudelman |
| work_keys_str_mv |
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| _version_ |
1807322448304013312 |