Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts
The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with...
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todo:paper_00162361_v149_n_p95_GenovevaZimicz2023-10-03T14:13:57Z Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts Genoveva Zimicz, M. Reznik, B.A. Larrondo, S.A. Biogas Ceria-based materials SOFCs Syngas Anodes Biogas Carbon dioxide Catalyst activity Catalysts Electrodes Fuel cells Greenhouse gases Methane Synthesis gas Carbonaceous compounds Catalytic behavior Catalytic performance Ceria based materials Feed compositions SOFCs Syn-gas Time on streams Solid oxide fuel cells (SOFC) The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with a stable behavior during a time on stream of six hours for a carbon dioxide to methane molar ratio of 2.3. This feed composition maximize the production of synthesis gas, with stable catalytic behavior without formation of carbonaceous compounds and involving CO2 capturing, contributing to the reduction of greenhouse gases. It can be concluded that NiO/CeO2Sm2O3 catalysts exhibited promising catalytic performance for their use in the composition of anode material of solid oxide fuel cells fed with biogas. ©2014 Elsevier Ltd. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00162361_v149_n_p95_GenovevaZimicz |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Biogas Ceria-based materials SOFCs Syngas Anodes Biogas Carbon dioxide Catalyst activity Catalysts Electrodes Fuel cells Greenhouse gases Methane Synthesis gas Carbonaceous compounds Catalytic behavior Catalytic performance Ceria based materials Feed compositions SOFCs Syn-gas Time on streams Solid oxide fuel cells (SOFC) |
spellingShingle |
Biogas Ceria-based materials SOFCs Syngas Anodes Biogas Carbon dioxide Catalyst activity Catalysts Electrodes Fuel cells Greenhouse gases Methane Synthesis gas Carbonaceous compounds Catalytic behavior Catalytic performance Ceria based materials Feed compositions SOFCs Syn-gas Time on streams Solid oxide fuel cells (SOFC) Genoveva Zimicz, M. Reznik, B.A. Larrondo, S.A. Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts |
topic_facet |
Biogas Ceria-based materials SOFCs Syngas Anodes Biogas Carbon dioxide Catalyst activity Catalysts Electrodes Fuel cells Greenhouse gases Methane Synthesis gas Carbonaceous compounds Catalytic behavior Catalytic performance Ceria based materials Feed compositions SOFCs Syn-gas Time on streams Solid oxide fuel cells (SOFC) |
description |
The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with a stable behavior during a time on stream of six hours for a carbon dioxide to methane molar ratio of 2.3. This feed composition maximize the production of synthesis gas, with stable catalytic behavior without formation of carbonaceous compounds and involving CO2 capturing, contributing to the reduction of greenhouse gases. It can be concluded that NiO/CeO2Sm2O3 catalysts exhibited promising catalytic performance for their use in the composition of anode material of solid oxide fuel cells fed with biogas. ©2014 Elsevier Ltd. All rights reserved. |
format |
JOUR |
author |
Genoveva Zimicz, M. Reznik, B.A. Larrondo, S.A. |
author_facet |
Genoveva Zimicz, M. Reznik, B.A. Larrondo, S.A. |
author_sort |
Genoveva Zimicz, M. |
title |
Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts |
title_short |
Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts |
title_full |
Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts |
title_fullStr |
Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts |
title_full_unstemmed |
Conversion of biogas to synthesis gas over NiO/CeO2-Sm2O3 catalysts |
title_sort |
conversion of biogas to synthesis gas over nio/ceo2-sm2o3 catalysts |
url |
http://hdl.handle.net/20.500.12110/paper_00162361_v149_n_p95_GenovevaZimicz |
work_keys_str_mv |
AT genovevazimiczm conversionofbiogastosynthesisgasovernioceo2sm2o3catalysts AT reznikba conversionofbiogastosynthesisgasovernioceo2sm2o3catalysts AT larrondosa conversionofbiogastosynthesisgasovernioceo2sm2o3catalysts |
_version_ |
1807316678884720640 |