1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions

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Pterins belong to a family of heterocyclic compounds present in a wide range of living systems and participate in relevant biological functions. Under anaerobic conditions, the unstable red intermediate generated by UV-A irradiation of biopterin, neopterin and 6-hydroxymethylpterin was identified by...

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Autores principales:	Vignoni, M., Salum, M.L., Erra-Balsells, R., Thomas, A.H., Cabrerizo, F.M.
Formato:	JOUR
Materias:	Anaerobic conditions Aqueous solutions Biological functions Biopterin Heterocyclic compound Living systems Neopterin NMR analysis Nuclear magnetic resonance
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00092614_v484_n4-6_p330_Vignoni
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00092614_v484_n4-6_p330_Vignoni
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spelling	todo:paper_00092614_v484_n4-6_p330_Vignoni2023-10-03T14:08:29Z 1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions Vignoni, M. Salum, M.L. Erra-Balsells, R. Thomas, A.H. Cabrerizo, F.M. Anaerobic conditions Aqueous solutions Biological functions Biopterin Heterocyclic compound Living systems Neopterin NMR analysis Nuclear magnetic resonance Pterins belong to a family of heterocyclic compounds present in a wide range of living systems and participate in relevant biological functions. Under anaerobic conditions, the unstable red intermediate generated by UV-A irradiation of biopterin, neopterin and 6-hydroxymethylpterin was identified by 1H NMR analysis, in alkaline D2O solutions, as 5,8-dihydro-6-formylpterin. © 2009 Elsevier B.V. All rights reserved. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00092614_v484_n4-6_p330_Vignoni
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Anaerobic conditions Aqueous solutions Biological functions Biopterin Heterocyclic compound Living systems Neopterin NMR analysis Nuclear magnetic resonance
spellingShingle	Anaerobic conditions Aqueous solutions Biological functions Biopterin Heterocyclic compound Living systems Neopterin NMR analysis Nuclear magnetic resonance Vignoni, M. Salum, M.L. Erra-Balsells, R. Thomas, A.H. Cabrerizo, F.M. 1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
topic_facet	Anaerobic conditions Aqueous solutions Biological functions Biopterin Heterocyclic compound Living systems Neopterin NMR analysis Nuclear magnetic resonance
description	Pterins belong to a family of heterocyclic compounds present in a wide range of living systems and participate in relevant biological functions. Under anaerobic conditions, the unstable red intermediate generated by UV-A irradiation of biopterin, neopterin and 6-hydroxymethylpterin was identified by 1H NMR analysis, in alkaline D2O solutions, as 5,8-dihydro-6-formylpterin. © 2009 Elsevier B.V. All rights reserved.
format	JOUR
author	Vignoni, M. Salum, M.L. Erra-Balsells, R. Thomas, A.H. Cabrerizo, F.M.
author_facet	Vignoni, M. Salum, M.L. Erra-Balsells, R. Thomas, A.H. Cabrerizo, F.M.
author_sort	Vignoni, M.
title	1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
title_short	1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
title_full	1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
title_fullStr	1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
title_full_unstemmed	1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
title_sort	1h nmr characterization of the intermediate formed upon uv-a excitation of biopterin, neopterin and 6-hydroxymethylpterin in o2-free aqueous solutions
url	http://hdl.handle.net/20.500.12110/paper_00092614_v484_n4-6_p330_Vignoni
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1H NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions

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