Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose

The reaction of methanolic ammonia with the hexa-O-acetyl and hexa-O-benzoyl derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose affords the 1,1-bis(acylamido)-1-deoxy-D-heptitols (2,3), from which the acetates have been prepared. The yields of 2 and 3...

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Autores principales: Deferrari, J.O., de Lederkremer, R.M.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v4_n5_p365_Deferrari
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00086215_v4_n5_p365_Deferrari2023-10-03T14:07:37Z Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose Deferrari, J.O. de Lederkremer, R.M. The reaction of methanolic ammonia with the hexa-O-acetyl and hexa-O-benzoyl derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose affords the 1,1-bis(acylamido)-1-deoxy-D-heptitols (2,3), from which the acetates have been prepared. The yields of 2 and 3 are in general higher than those of the corresponding hexose derivatives. On ammonolysis of hexa-O-benzoyl-D-glycero-L-manno-heptose, an N-benzoyl-D-glycero-L-manno-heptosylamine is formed, together with the main product. © 1967. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:de Lederkremer, R.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v4_n5_p365_Deferrari
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The reaction of methanolic ammonia with the hexa-O-acetyl and hexa-O-benzoyl derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose affords the 1,1-bis(acylamido)-1-deoxy-D-heptitols (2,3), from which the acetates have been prepared. The yields of 2 and 3 are in general higher than those of the corresponding hexose derivatives. On ammonolysis of hexa-O-benzoyl-D-glycero-L-manno-heptose, an N-benzoyl-D-glycero-L-manno-heptosylamine is formed, together with the main product. © 1967.
format JOUR
author Deferrari, J.O.
de Lederkremer, R.M.
spellingShingle Deferrari, J.O.
de Lederkremer, R.M.
Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
author_facet Deferrari, J.O.
de Lederkremer, R.M.
author_sort Deferrari, J.O.
title Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
title_short Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
title_full Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
title_fullStr Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
title_full_unstemmed Reaction of ammonia with acylated aldoheptoses. Derivatives of D-glycero-D-gulo-heptose, D-glycero-L-manno-heptose, and D-glycero-D-galacto-heptose
title_sort reaction of ammonia with acylated aldoheptoses. derivatives of d-glycero-d-gulo-heptose, d-glycero-l-manno-heptose, and d-glycero-d-galacto-heptose
url http://hdl.handle.net/20.500.12110/paper_00086215_v4_n5_p365_Deferrari
work_keys_str_mv AT deferrarijo reactionofammoniawithacylatedaldoheptosesderivativesofdglycerodguloheptosedglycerolmannoheptoseanddglycerodgalactoheptose
AT delederkremerrm reactionofammoniawithacylatedaldoheptosesderivativesofdglycerodguloheptosedglycerolmannoheptoseanddglycerodgalactoheptose
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