Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight mass spectrometry (UV-MALDI-TOF-MS) has shown to be a very useful technique for the study of the non-volatile and thermally non-stable N-acylated glycopyranosyl- and glycofuranosyl-amines. Of the several matrices tested, 2,5-dihy...
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todo:paper_00086215_v342_n17_p2567_Sato2023-10-03T14:07:16Z Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines Sato, Y. Fukuyama, Y. Nonami, H. Erra-Balsells, R. Stortz, C.A. Cerezo, A.S. Matulewicz, M.C. N,O-Acylated glycosylamines N-Acylated glycosylamines PSD UV-MALDI-TOF-MS UV-MALDI-TOF-MS Fragment ions N,O-Acylated glycosylamines N-Acylated glycosylamines Amines Ionization Mass spectrometers Mass spectrometry aminoglycoside derivative gentisic acid monosaccharide n acylated glycosylamine n o acylated glycosylamine unclassified drug article carbohydrate analysis electron ionization mass spectrometry fragmentation reaction mass fragmentography matrix assisted ultraviolet laser desorption ionization time of flight mass spectrometry post source decay priority journal time of flight mass spectrometry Acetylation Amines Calibration Chemistry, Organic Gentisates Models, Chemical Nitrogen Oligosaccharides Oxygen Solvents Spectrometry, Mass, Electrospray Ionization Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization Spectrophotometry, Ultraviolet Ultraviolet Rays Matrix-assisted ultraviolet laser desorption/ionization time-of-flight mass spectrometry (UV-MALDI-TOF-MS) has shown to be a very useful technique for the study of the non-volatile and thermally non-stable N-acylated glycopyranosyl- and glycofuranosyl-amines. Of the several matrices tested, 2,5-dihydroxybenzoic acid (DHB) was the most effective giving good spectra in the positive-ion mode. In the linear and reflectron modes, the [M+Na]+ ions appeared with high intensity. Their fragmentation patterns were investigated by post-source decay (PSD) UV-MALDI-TOF-MS showing mainly cross-ring cleavages. In addition, N,O-acylated glycopyranosyl- and glycofuranosyl-amines were also analyzed by this technique. PSD UV-MALDI-TOF-MS gave significant signals for several primary fragment ions, which were proposed but not detected, or observed with very low abundance, in electron ionization mass spectrometry (EI-MS) experiments. © 2007 Elsevier Ltd. All rights reserved. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Stortz, C.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cerezo, A.S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Matulewicz, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v342_n17_p2567_Sato |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
N,O-Acylated glycosylamines N-Acylated glycosylamines PSD UV-MALDI-TOF-MS UV-MALDI-TOF-MS Fragment ions N,O-Acylated glycosylamines N-Acylated glycosylamines Amines Ionization Mass spectrometers Mass spectrometry aminoglycoside derivative gentisic acid monosaccharide n acylated glycosylamine n o acylated glycosylamine unclassified drug article carbohydrate analysis electron ionization mass spectrometry fragmentation reaction mass fragmentography matrix assisted ultraviolet laser desorption ionization time of flight mass spectrometry post source decay priority journal time of flight mass spectrometry Acetylation Amines Calibration Chemistry, Organic Gentisates Models, Chemical Nitrogen Oligosaccharides Oxygen Solvents Spectrometry, Mass, Electrospray Ionization Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization Spectrophotometry, Ultraviolet Ultraviolet Rays |
spellingShingle |
N,O-Acylated glycosylamines N-Acylated glycosylamines PSD UV-MALDI-TOF-MS UV-MALDI-TOF-MS Fragment ions N,O-Acylated glycosylamines N-Acylated glycosylamines Amines Ionization Mass spectrometers Mass spectrometry aminoglycoside derivative gentisic acid monosaccharide n acylated glycosylamine n o acylated glycosylamine unclassified drug article carbohydrate analysis electron ionization mass spectrometry fragmentation reaction mass fragmentography matrix assisted ultraviolet laser desorption ionization time of flight mass spectrometry post source decay priority journal time of flight mass spectrometry Acetylation Amines Calibration Chemistry, Organic Gentisates Models, Chemical Nitrogen Oligosaccharides Oxygen Solvents Spectrometry, Mass, Electrospray Ionization Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization Spectrophotometry, Ultraviolet Ultraviolet Rays Sato, Y. Fukuyama, Y. Nonami, H. Erra-Balsells, R. Stortz, C.A. Cerezo, A.S. Matulewicz, M.C. Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines |
topic_facet |
N,O-Acylated glycosylamines N-Acylated glycosylamines PSD UV-MALDI-TOF-MS UV-MALDI-TOF-MS Fragment ions N,O-Acylated glycosylamines N-Acylated glycosylamines Amines Ionization Mass spectrometers Mass spectrometry aminoglycoside derivative gentisic acid monosaccharide n acylated glycosylamine n o acylated glycosylamine unclassified drug article carbohydrate analysis electron ionization mass spectrometry fragmentation reaction mass fragmentography matrix assisted ultraviolet laser desorption ionization time of flight mass spectrometry post source decay priority journal time of flight mass spectrometry Acetylation Amines Calibration Chemistry, Organic Gentisates Models, Chemical Nitrogen Oligosaccharides Oxygen Solvents Spectrometry, Mass, Electrospray Ionization Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization Spectrophotometry, Ultraviolet Ultraviolet Rays |
description |
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight mass spectrometry (UV-MALDI-TOF-MS) has shown to be a very useful technique for the study of the non-volatile and thermally non-stable N-acylated glycopyranosyl- and glycofuranosyl-amines. Of the several matrices tested, 2,5-dihydroxybenzoic acid (DHB) was the most effective giving good spectra in the positive-ion mode. In the linear and reflectron modes, the [M+Na]+ ions appeared with high intensity. Their fragmentation patterns were investigated by post-source decay (PSD) UV-MALDI-TOF-MS showing mainly cross-ring cleavages. In addition, N,O-acylated glycopyranosyl- and glycofuranosyl-amines were also analyzed by this technique. PSD UV-MALDI-TOF-MS gave significant signals for several primary fragment ions, which were proposed but not detected, or observed with very low abundance, in electron ionization mass spectrometry (EI-MS) experiments. © 2007 Elsevier Ltd. All rights reserved. |
format |
JOUR |
author |
Sato, Y. Fukuyama, Y. Nonami, H. Erra-Balsells, R. Stortz, C.A. Cerezo, A.S. Matulewicz, M.C. |
author_facet |
Sato, Y. Fukuyama, Y. Nonami, H. Erra-Balsells, R. Stortz, C.A. Cerezo, A.S. Matulewicz, M.C. |
author_sort |
Sato, Y. |
title |
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines |
title_short |
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines |
title_full |
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines |
title_fullStr |
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines |
title_full_unstemmed |
Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines |
title_sort |
matrix-assisted ultraviolet laser desorption/ionization time-of-flight (uv-maldi-tof) mass spectra of n-acylated and n,o-acylated glycosylamines |
url |
http://hdl.handle.net/20.500.12110/paper_00086215_v342_n17_p2567_Sato |
work_keys_str_mv |
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