Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene
The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation...
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todo:paper_00027863_v84_n6_p1026_Greizerstein2023-10-03T13:54:33Z Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene Greizerstein, W. Bonelli, R.A. Brieux, J.A. The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation energies. © 1962, American Chemical Society. All rights reserved. Fil:Greizerstein, W. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bonelli, R.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Brieux, J.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00027863_v84_n6_p1026_Greizerstein |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation energies. © 1962, American Chemical Society. All rights reserved. |
format |
JOUR |
author |
Greizerstein, W. Bonelli, R.A. Brieux, J.A. |
spellingShingle |
Greizerstein, W. Bonelli, R.A. Brieux, J.A. Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
author_facet |
Greizerstein, W. Bonelli, R.A. Brieux, J.A. |
author_sort |
Greizerstein, W. |
title |
Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
title_short |
Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
title_full |
Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
title_fullStr |
Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
title_full_unstemmed |
Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
title_sort |
polar effects of substitutents on the reaction rates of 4-r- and 5-r-2-nitrochlorobenzenes with piperidine in benzene |
url |
http://hdl.handle.net/20.500.12110/paper_00027863_v84_n6_p1026_Greizerstein |
work_keys_str_mv |
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