The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]

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The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordinat...

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Autores principales: Baggio, R., Garland, M.T., Perec, M.
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: 1996
Materias:
Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paperaa:paper_01082701_v52_n4_p823_Baggio2023-06-12T16:46:32Z The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br] Acta Crystallogr Sect C Cryst Struct Commun 1996;52(4):823-826 Baggio, R. Garland, M.T. Perec, M. Bromine compounds Cadmium compounds Chlorine compounds Crystal atomic structure Molecular structure Spectroscopic analysis Cadmium halide bis(diethyldithiocarbamate) complexes Isomorphous compounds Mononuclear complexes Organometallics The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1996 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion application/pdf eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
language Inglés
orig_language_str_mv eng
topic Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
spellingShingle Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
Baggio, R.
Garland, M.T.
Perec, M.
The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
topic_facet Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
description The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively.
format Artículo
Artículo
publishedVersion
author Baggio, R.
Garland, M.T.
Perec, M.
author_facet Baggio, R.
Garland, M.T.
Perec, M.
author_sort Baggio, R.
title The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_short The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_fullStr The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full_unstemmed The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_sort five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [pph4][cd(s2cnet2)2cl] and [pph4][cd(s2cnet2)2br]
publishDate 1996
url http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
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