The role of viscosity on ion transport in thin-layer electrodeposition

The effects of viscosity variation on ion transport and growth morphology, under constant electric current and convection prevailing regimes , is studied through experiments and computational modeling. The viscosity was changed through glycerol addition. Optical techniques and particle image velocim...

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Autores principales: Gonzalez, Graciela Alicia, Molina, Fernando Victor, Dengra, Silvina, Sánchez, Aníbal Horacio
Publicado: 2001
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_NIS01843_v8_n_p43_Gonzalez
http://hdl.handle.net/20.500.12110/paper_NIS01843_v8_n_p43_Gonzalez
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spelling paper:paper_NIS01843_v8_n_p43_Gonzalez2023-06-08T16:39:27Z The role of viscosity on ion transport in thin-layer electrodeposition Gonzalez, Graciela Alicia Molina, Fernando Victor Dengra, Silvina Sánchez, Aníbal Horacio Charge transfer Concentration (process) Electric currents Electrolytes Fractals Solutions Velocity measurement Viscosity Computational modeling Electrostatic potential Ion transport Viscosity variations Electrodeposition The effects of viscosity variation on ion transport and growth morphology, under constant electric current and convection prevailing regimes , is studied through experiments and computational modeling. The viscosity was changed through glycerol addition. Optical techniques and particle image velocimetry using micron sized particles, allowed the tracking of the convective, migration and concentration fronts and the measurement of fluid velocity. Computational modeling is based on a macroscopic model describing the coupling of ion transport, electrostatic potential and fluid flow. Experimental results and computational modeling show that concentration and convective fronts slow down with viscosity, but their time scaling follows the same law as for pure aqueous solutions. Velocity measurements reveal that increasing viscosity the intensity of gravitoconvective motion decreases, while gravitoconvection becomes relatively stronger. Fil:Gonzalez, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Molina, F.V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Dengra, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Sanchez, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2001 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_NIS01843_v8_n_p43_Gonzalez http://hdl.handle.net/20.500.12110/paper_NIS01843_v8_n_p43_Gonzalez
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Charge transfer
Concentration (process)
Electric currents
Electrolytes
Fractals
Solutions
Velocity measurement
Viscosity
Computational modeling
Electrostatic potential
Ion transport
Viscosity variations
Electrodeposition
spellingShingle Charge transfer
Concentration (process)
Electric currents
Electrolytes
Fractals
Solutions
Velocity measurement
Viscosity
Computational modeling
Electrostatic potential
Ion transport
Viscosity variations
Electrodeposition
Gonzalez, Graciela Alicia
Molina, Fernando Victor
Dengra, Silvina
Sánchez, Aníbal Horacio
The role of viscosity on ion transport in thin-layer electrodeposition
topic_facet Charge transfer
Concentration (process)
Electric currents
Electrolytes
Fractals
Solutions
Velocity measurement
Viscosity
Computational modeling
Electrostatic potential
Ion transport
Viscosity variations
Electrodeposition
description The effects of viscosity variation on ion transport and growth morphology, under constant electric current and convection prevailing regimes , is studied through experiments and computational modeling. The viscosity was changed through glycerol addition. Optical techniques and particle image velocimetry using micron sized particles, allowed the tracking of the convective, migration and concentration fronts and the measurement of fluid velocity. Computational modeling is based on a macroscopic model describing the coupling of ion transport, electrostatic potential and fluid flow. Experimental results and computational modeling show that concentration and convective fronts slow down with viscosity, but their time scaling follows the same law as for pure aqueous solutions. Velocity measurements reveal that increasing viscosity the intensity of gravitoconvective motion decreases, while gravitoconvection becomes relatively stronger.
author Gonzalez, Graciela Alicia
Molina, Fernando Victor
Dengra, Silvina
Sánchez, Aníbal Horacio
author_facet Gonzalez, Graciela Alicia
Molina, Fernando Victor
Dengra, Silvina
Sánchez, Aníbal Horacio
author_sort Gonzalez, Graciela Alicia
title The role of viscosity on ion transport in thin-layer electrodeposition
title_short The role of viscosity on ion transport in thin-layer electrodeposition
title_full The role of viscosity on ion transport in thin-layer electrodeposition
title_fullStr The role of viscosity on ion transport in thin-layer electrodeposition
title_full_unstemmed The role of viscosity on ion transport in thin-layer electrodeposition
title_sort role of viscosity on ion transport in thin-layer electrodeposition
publishDate 2001
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_NIS01843_v8_n_p43_Gonzalez
http://hdl.handle.net/20.500.12110/paper_NIS01843_v8_n_p43_Gonzalez
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