A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity
The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to c...
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2019
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20734360_v11_n2_p_LeonBoigues http://hdl.handle.net/20.500.12110/paper_20734360_v11_n2_p_LeonBoigues |
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paper:paper_20734360_v11_n2_p_LeonBoigues2023-06-08T16:34:11Z A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young's modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture. © 2019 by the authors. 2019 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20734360_v11_n2_p_LeonBoigues http://hdl.handle.net/20.500.12110/paper_20734360_v11_n2_p_LeonBoigues |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide |
| spellingShingle |
Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| topic_facet |
Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide |
| description |
The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young's modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture. © 2019 by the authors. |
| title |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_short |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_full |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_fullStr |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_full_unstemmed |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_sort |
patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| publishDate |
2019 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20734360_v11_n2_p_LeonBoigues http://hdl.handle.net/20.500.12110/paper_20734360_v11_n2_p_LeonBoigues |
| _version_ |
1768543106146238464 |