The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion

We report herein the synthesis, crystallographic analysis and a study of the non-covalent interactions observed in the new 4′-substituted terpyridine-based derivative bis[4′-(isoquinolin-2-ium-4-yl)-4,2′:6′,4′′-terpyridine-1,1′′-diium] tris-[tetrachloridozincate(II)], (C24H19N4)2[ZnCl4]3 or (44TPH3)...

Descripción completa

Guardado en:
Detalles Bibliográficos
Publicado: 2018
Materias:
Anion⋯π interactions
crystal structure
Hirshfeld surfaces
terpyridine
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20569890_v74_n_p1881_Granifo
http://hdl.handle.net/20.500.12110/paper_20569890_v74_n_p1881_Granifo
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_20569890_v74_n_p1881_Granifo
record_format dspace
spelling paper:paper_20569890_v74_n_p1881_Granifo2023-06-08T16:34:07Z The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion Anion⋯π interactions crystal structure Hirshfeld surfaces terpyridine We report herein the synthesis, crystallographic analysis and a study of the non-covalent interactions observed in the new 4′-substituted terpyridine-based derivative bis[4′-(isoquinolin-2-ium-4-yl)-4,2′:6′,4′′-terpyridine-1,1′′-diium] tris-[tetrachloridozincate(II)], (C24H19N4)2[ZnCl4]3 or (44TPH3)2[ZnCl4]3, where (44TPH3)3+ is the triply protonated cation 4′-(isoquinolinium-4-yl)-4,2′:6′,4′′ terpyridinium. The compound is similar in its formulation to the recently reported 2,2′:6′,2′′ terpyridinium analogue {bis[4′-(isoquinolin-2-ium-4-yl)-2,2′:6′,2′′-terpyridine-1,1′′-diium] tris[tetrachloridozincate(II)] monohydrate; Granifo et al. (2017). Acta Cryst. C73, 1121-1130}, although rather different and much simpler in its structural features, mainly in the number and type of non-covalent interactions present, as well as in the supramolecular structure they define. © 2018 International Union of Crystallography. All rights reserved. 2018 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20569890_v74_n_p1881_Granifo http://hdl.handle.net/20.500.12110/paper_20569890_v74_n_p1881_Granifo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Anion⋯π interactions
crystal structure
Hirshfeld surfaces
terpyridine
spellingShingle Anion⋯π interactions
crystal structure
Hirshfeld surfaces
terpyridine
The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
topic_facet Anion⋯π interactions
crystal structure
Hirshfeld surfaces
terpyridine
description We report herein the synthesis, crystallographic analysis and a study of the non-covalent interactions observed in the new 4′-substituted terpyridine-based derivative bis[4′-(isoquinolin-2-ium-4-yl)-4,2′:6′,4′′-terpyridine-1,1′′-diium] tris-[tetrachloridozincate(II)], (C24H19N4)2[ZnCl4]3 or (44TPH3)2[ZnCl4]3, where (44TPH3)3+ is the triply protonated cation 4′-(isoquinolinium-4-yl)-4,2′:6′,4′′ terpyridinium. The compound is similar in its formulation to the recently reported 2,2′:6′,2′′ terpyridinium analogue {bis[4′-(isoquinolin-2-ium-4-yl)-2,2′:6′,2′′-terpyridine-1,1′′-diium] tris[tetrachloridozincate(II)] monohydrate; Granifo et al. (2017). Acta Cryst. C73, 1121-1130}, although rather different and much simpler in its structural features, mainly in the number and type of non-covalent interactions present, as well as in the supramolecular structure they define. © 2018 International Union of Crystallography. All rights reserved.
title The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
title_short The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
title_full The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
title_fullStr The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
title_full_unstemmed The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
title_sort enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [zncl4]2- as counter-ion
publishDate 2018
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20569890_v74_n_p1881_Granifo
http://hdl.handle.net/20.500.12110/paper_20569890_v74_n_p1881_Granifo
_version_ 1768544660666449920

Ejemplares similares