A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to th...
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2015
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v71_n_p294_Paz http://hdl.handle.net/20.500.12110/paper_20532296_v71_n_p294_Paz |
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paper:paper_20532296_v71_n_p294_Paz2023-06-08T16:34:02Z A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism Suarez, Sebastian Dendocarbin A Drimys winteri extract isostructural polymorphism monoclinic polymorphic form crystal structure natural product sesquiterpene lactone Esters Dendocarbin A Drimys winteri extract Isostructural Natural products Polymorphic forms Sesquiterpene lactones Crystal structure Drimys winteri dendocarbin A lactone sesquiterpene chemical structure chemistry crystallization Drimys isolation and purification Crystallization Drimys Lactones Molecular Structure Sesquiterpenes The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism. © 2015 International Union of Crystallography. Fil:Suarez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v71_n_p294_Paz http://hdl.handle.net/20.500.12110/paper_20532296_v71_n_p294_Paz |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Dendocarbin A Drimys winteri extract isostructural polymorphism monoclinic polymorphic form crystal structure natural product sesquiterpene lactone Esters Dendocarbin A Drimys winteri extract Isostructural Natural products Polymorphic forms Sesquiterpene lactones Crystal structure Drimys winteri dendocarbin A lactone sesquiterpene chemical structure chemistry crystallization Drimys isolation and purification Crystallization Drimys Lactones Molecular Structure Sesquiterpenes |
| spellingShingle |
Dendocarbin A Drimys winteri extract isostructural polymorphism monoclinic polymorphic form crystal structure natural product sesquiterpene lactone Esters Dendocarbin A Drimys winteri extract Isostructural Natural products Polymorphic forms Sesquiterpene lactones Crystal structure Drimys winteri dendocarbin A lactone sesquiterpene chemical structure chemistry crystallization Drimys isolation and purification Crystallization Drimys Lactones Molecular Structure Sesquiterpenes Suarez, Sebastian A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism |
| topic_facet |
Dendocarbin A Drimys winteri extract isostructural polymorphism monoclinic polymorphic form crystal structure natural product sesquiterpene lactone Esters Dendocarbin A Drimys winteri extract Isostructural Natural products Polymorphic forms Sesquiterpene lactones Crystal structure Drimys winteri dendocarbin A lactone sesquiterpene chemical structure chemistry crystallization Drimys isolation and purification Crystallization Drimys Lactones Molecular Structure Sesquiterpenes |
| description |
The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism. © 2015 International Union of Crystallography. |
| author |
Suarez, Sebastian |
| author_facet |
Suarez, Sebastian |
| author_sort |
Suarez, Sebastian |
| title |
A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism |
| title_short |
A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism |
| title_full |
A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism |
| title_fullStr |
A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism |
| title_full_unstemmed |
A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism |
| title_sort |
monoclinic form of dendocarbin a: a borderline case of one-dimensional isostructural polymorphism |
| publishDate |
2015 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v71_n_p294_Paz http://hdl.handle.net/20.500.12110/paper_20532296_v71_n_p294_Paz |
| work_keys_str_mv |
AT suarezsebastian amonoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism AT suarezsebastian monoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism |
| _version_ |
1768542619136163840 |