Perfluoroalkylation reactions of (hetero)arenes

Perfluoroalkylation reactions of arenes have not been the subject of intense study as has been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic methods proposed for achieving homolytic aromatic substitution reactions with perfluoroalkyl moieties have begun to...

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Detalles Bibliográficos
Autor principal:	Bonesi, Sergio Mauricio
Publicado:	2015
Materias:	Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20462069_v5_n77_p62498_BarataVallejo http://hdl.handle.net/20.500.12110/paper_20462069_v5_n77_p62498_BarataVallejo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_20462069_v5_n77_p62498_BarataVallejo
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spelling	paper:paper_20462069_v5_n77_p62498_BarataVallejo2023-06-08T16:33:45Z Perfluoroalkylation reactions of (hetero)arenes Bonesi, Sergio Mauricio Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions Perfluoroalkylation reactions of arenes have not been the subject of intense study as has been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic methods proposed for achieving homolytic aromatic substitution reactions with perfluoroalkyl moieties have begun to claim a relevant role in functionalization reactions, as revealed by the interesting properties of arenes with large perfluoroalkyl chains. Methods for achieving Ar-R<inf>f</inf> bonding reactions can be classified into thermal and photochemical, which can in turn make use of transition metals or be non-metal catalyzed. Reactions are mainly radical in nature. Radical methods for introducing R<inf>f</inf> moieties into arenes have resulted as being the most popular and versatile options available to synthetic chemists. © The Royal Society of Chemistry 2015. Fil:Bonesi, S.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20462069_v5_n77_p62498_BarataVallejo http://hdl.handle.net/20.500.12110/paper_20462069_v5_n77_p62498_BarataVallejo
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions
spellingShingle	Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions Bonesi, Sergio Mauricio Perfluoroalkylation reactions of (hetero)arenes
topic_facet	Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions
description	Perfluoroalkylation reactions of arenes have not been the subject of intense study as has been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic methods proposed for achieving homolytic aromatic substitution reactions with perfluoroalkyl moieties have begun to claim a relevant role in functionalization reactions, as revealed by the interesting properties of arenes with large perfluoroalkyl chains. Methods for achieving Ar-R<inf>f</inf> bonding reactions can be classified into thermal and photochemical, which can in turn make use of transition metals or be non-metal catalyzed. Reactions are mainly radical in nature. Radical methods for introducing R<inf>f</inf> moieties into arenes have resulted as being the most popular and versatile options available to synthetic chemists. © The Royal Society of Chemistry 2015.
author	Bonesi, Sergio Mauricio
author_facet	Bonesi, Sergio Mauricio
author_sort	Bonesi, Sergio Mauricio
title	Perfluoroalkylation reactions of (hetero)arenes
title_short	Perfluoroalkylation reactions of (hetero)arenes
title_full	Perfluoroalkylation reactions of (hetero)arenes
title_fullStr	Perfluoroalkylation reactions of (hetero)arenes
title_full_unstemmed	Perfluoroalkylation reactions of (hetero)arenes
title_sort	perfluoroalkylation reactions of (hetero)arenes
publishDate	2015
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20462069_v5_n77_p62498_BarataVallejo http://hdl.handle.net/20.500.12110/paper_20462069_v5_n77_p62498_BarataVallejo
work_keys_str_mv	AT bonesisergiomauricio perfluoroalkylationreactionsofheteroarenes
_version_	1768543535610462208

Perfluoroalkylation reactions of (hetero)arenes

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