Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc

The molecular structure of the title compound, [Zn(CH3COO) 2(C12H12N2)], consists of isolated molecules bisected by a twofold rotation axis which goes through the ZnII cation and halves the organic base through the central C-C bond. The Zn II ion is coordinated by two N atoms from one molecule of th...

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Detalles Bibliográficos
Autores principales: Suarez, Sebastian, Doctorovich, Fabio Ariel
Publicado: 2012
Materias:
data-to-parameter ratio = 14.6
mean ̄(C-C) = 0.004 Å
R factor = 0.026
single-crystal X-ray study
T = 295 K
wR factor = 0.068
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v68_n11_pm1377_Harvey
http://hdl.handle.net/20.500.12110/paper_16005368_v68_n11_pm1377_Harvey
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_16005368_v68_n11_pm1377_Harvey
record_format dspace
spelling paper:paper_16005368_v68_n11_pm1377_Harvey2025-07-30T19:00:36Z Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc Suarez, Sebastian Doctorovich, Fabio Ariel data-to-parameter ratio = 14.6 mean ̄(C-C) = 0.004 Å R factor = 0.026 single-crystal X-ray study T = 295 K wR factor = 0.068 The molecular structure of the title compound, [Zn(CH3COO) 2(C12H12N2)], consists of isolated molecules bisected by a twofold rotation axis which goes through the ZnII cation and halves the organic base through the central C-C bond. The Zn II ion is coordinated by two N atoms from one molecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asymmetrically [Zn-O distances of 2.058(2) and 2.362(3)Å], while the two Zn-N bond distances are equal as imposed by symmetry [2.079(2)Å]. The crystal structure is supported by a number of weak C-H⋯O interactions and C-H⋯π contacts, with no π-π interactions present, mainly hindered by the substituent methyl groups and the relative molecular orientation. The result is a three-dimensional structure in which each molecule is linked to eight different neighbors. Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2012 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v68_n11_pm1377_Harvey http://hdl.handle.net/20.500.12110/paper_16005368_v68_n11_pm1377_Harvey
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic data-to-parameter ratio = 14.6
mean ̄(C-C) = 0.004 Å
R factor = 0.026
single-crystal X-ray study
T = 295 K
wR factor = 0.068
spellingShingle data-to-parameter ratio = 14.6
mean ̄(C-C) = 0.004 Å
R factor = 0.026
single-crystal X-ray study
T = 295 K
wR factor = 0.068
Suarez, Sebastian
Doctorovich, Fabio Ariel
Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
topic_facet data-to-parameter ratio = 14.6
mean ̄(C-C) = 0.004 Å
R factor = 0.026
single-crystal X-ray study
T = 295 K
wR factor = 0.068
description The molecular structure of the title compound, [Zn(CH3COO) 2(C12H12N2)], consists of isolated molecules bisected by a twofold rotation axis which goes through the ZnII cation and halves the organic base through the central C-C bond. The Zn II ion is coordinated by two N atoms from one molecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asymmetrically [Zn-O distances of 2.058(2) and 2.362(3)Å], while the two Zn-N bond distances are equal as imposed by symmetry [2.079(2)Å]. The crystal structure is supported by a number of weak C-H⋯O interactions and C-H⋯π contacts, with no π-π interactions present, mainly hindered by the substituent methyl groups and the relative molecular orientation. The result is a three-dimensional structure in which each molecule is linked to eight different neighbors.
author Suarez, Sebastian
Doctorovich, Fabio Ariel
author_facet Suarez, Sebastian
Doctorovich, Fabio Ariel
author_sort Suarez, Sebastian
title Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
title_short Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
title_full Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
title_fullStr Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
title_full_unstemmed Bis(acetato-κ2 O,O')(4,4′-dimethyl-2,2′- bipyridine-κ2 N,N')zinc
title_sort bis(acetato-κ2 o,o')(4,4′-dimethyl-2,2′- bipyridine-κ2 n,n')zinc
publishDate 2012
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v68_n11_pm1377_Harvey
http://hdl.handle.net/20.500.12110/paper_16005368_v68_n11_pm1377_Harvey
work_keys_str_mv AT suarezsebastian bisacetatok2oo44dimethyl22bipyridinek2nnzinc
AT doctorovichfabioariel bisacetatok2oo44dimethyl22bipyridinek2nnzinc
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